explain how the kink in the characteristics as due to secondary emission from the anode
Secondary emission Secondary emission can be undesirable such as in the tetrode thermionic valve (tube). In this instance the positively charged screen grid can accelerate the electron stream sufficiently to cause secondary emission at the anode (plate). This can give rise to excessive screen grid current. It is also partly responsible for this type of valve (tube), particularly early types with anodes not treated to reduce secondary emission, exhibiting a 'negative resistance' characteristic, which could cause the tube to become unstable. This side effect could be put to use by using some older valves (e.g., type 77 pentode) as dynatron oscillators. This effect was prevented by adding a third grid to the tetrode, called the suppressor grid, to repel the electrons back toward the plate. This tube was called the pentode.
Electrophilic aromatic substitution Groups with unshared pairs of electrons, such as the amino group of aniline, are strongly activating and ortho/para-directing by resonance. Such activating groups donate those unshared electrons to the pi system, creating a negative charge on the ortho and para positions. These positions are thus the most reactive towards an electron-poor electrophile. The highest electron density is located on both ortho and para positions,[clarification needed] although this increased reactivity might be offset by steric hindrance between substituent and electrophile. The final result of the electrophilic aromatic substitution might thus be hard to predict, and it is usually only established by doing the reaction and determining the ratio of ortho versus para substitution.