when did the chinese first use gunpowder as a weapon
History of gunpowder At this point the formula contained too little saltpeter (about 50%) to be explosive, but the mixture was highly flammable, and contemporary weapons reflected this in their deployment as mainly shock and incendiary weapons. One of the first, if not the first of these weapons was the fire arrow.[13] The first possible reference to the use of fire arrows was by the Southern Wu in 904 during the siege of Yuzhang, when an officer under Yang Xingmi by the name of Zheng Fan (鄭璠) ordered his troops to "shoot off a machine to let fire and burn the Longsha Gate," after which he and his troops dashed over the fire into the city and captured it, and he was promoted to Prime Minister Inspectorate for his efforts and the burns his body endured.[14] A later account of this event corroborated with the report and explained that "by let fire (飛火) is meant things like firebombs and fire arrows."[13] Arrows carrying gunpowder was possibly the most applicable form of gunpowder weaponry at the time, as early gunpowder may have only produced an effective flame when exposed to oxygen, thus the rush of air around the arrow in flight would have provided a suitable catalyst for the reaction.[13]
LeMat Revolver The LeMat revolver was a .42 or .36 caliber cap & ball black powder revolver invented by Jean Alexandre LeMat of New Orleans, which featured an unusual secondary 20 gauge smooth-bore barrel capable of firing buckshot. It saw service with the armed forces of the Confederate States of America during the American Civil War of 1861â€“65 and the Army of the Government of National Defense during the Franco-Prussian War.