why are the brix readings of fermented solutions usually higher than unfermented beverages
Brix Alcohol has a higher refractive index (1.361) than water (1.333). As a consequence, a refractometer measurement made on a sugar solution once fermentation has begun will result in a reading substantially higher than the actual solids content. Thus, an operator must be certain that the sample he is testing has not begun to ferment. Brix or Plato measurements based on specific gravity are also affected by fermentation, but in the opposite direction; as ethanol is less dense than water, an ethanol/sugar/water solution gives a Brix or Plato reading which is artificially low.
Alcoholic drink The concentration of alcohol in a beverage is usually stated as the percentage of alcohol by volumeÂ  (ABV, the number of milliliters (ml) of pure ethanol in 100 ml of beverage) or as proof. In the United States, proof is twice the percentage of alcohol by volume at 60 degrees Fahrenheit (e.g. 80 proof = 40% ABV). Degrees proof were formerly used in the United Kingdom, where 100 degrees proof was equivalent to 57.1% ABV. Historically, this was the most dilute spirit that would sustain the combustion of gunpowder.