IMINIUM SALTS IN CLEANING COMPOSITIONSThis invention relates to organic catalysts comprising iminium or oxaziridinium moieties, cleaning compositions comprising such catalysts; and processes for making and using such catalysts and cleaning products.An organic catalyst having the following formula:wherein: Ri is a aryl or heteroaryl group that can be substituted or unsubstituted; R2 is a substituted or unsubstituted alkyl;Ri and R2 when taken together with the iminium form a ring, preferably a six membered ringR3 is a Ci to C20 substituted allcyl, preferably a to 2 substituted allcyl, more preferably a substituted C2 allcyl; R is the moiety Qt-A wherein: Q is a branched or unbranched allcylene, preferably a to C3 allcyl, t=0 or 1 andA is an anionic group selected from the group consisting ofOSO3', S03', CO2 OC02', OPO3 2 OPO3H. and OP02' ; preferably A is an anionic group selected from the group consisting of OS03 S03', C02', and OC02', preferably R is OSO3'; R5 is the moiety -CRπRi2-X-Gb-Xc-[(CR9Rι0)y-O]k-R8 wherein: each X is independently selected from the group consisting ofO, S, N-H, or N-R8; and each R8 is independently selected from the group consisting of allcyl, aryl and heteroaryl, said R8 moieties being substituted or unsubstituted, and whether substituted or unsubsituted said R8 moieties having less than 21 carbons; each G is independently selected from the group consisting ofCO, S02, SO, PO and P02;R9 and Ri0 are independently selected from the group consisting of H and C C4 allcyl; and Rn and RJ2 are independently selected from the group consisting of H and allcyl, or when taken together may join to form a carbonyl; and b = 0 or l; c can = 0 or 1, but c must = 0 if b = 0; y is an integer from 1 to 6; k is an integer from 0 to 20; preferably R5 is the moiety -CRπRi2-X-Gb-X0-R8 wherein: each X is independently selected from the group consisting ofO, S, N-H, or N-R8; and each R8 is independently selected from the group consisting of allcyl, aryl and heteroaryl, said R8 moieties being substituted or unsubstituted, and whether substituted or unsubsituted said R8 moieties having less than 21 carbons; each G is independently selected from the group consisting ofCO, S02, SO, PO and P02;Rn and Rι2 are independently selected from the group consisting of H and allcyl; b = 0 r l; c can = 0 or 1, but c must = 0 if b = 1, more preferably R5 is the moiety -CH2-0-R8 wherein each Rs is independently selected from the group consisting of allcyl, aryl and heteroaryl, said R8 moieties being substituted or unsubstituted, and whether substituted or unsubsituted said R8 moieties having less than 21 carbons and R6 is H, or an allcyl, aryl or heteroaryl moiety; said moieties being substituted or unsubstituted.An organic catalyst having the following formula: wherein: Rt is a aryl or heteroaryl group that can be substituted or unsubstituted;R2 is a substituted or unsubstituted allcyl;R] and R2 when taken together with the carbon and the nitrogen of the oxaziridinium form a ring, preferably a six member ring;R3 is a Ci to C20 substituted alkyl, preferably a to C substituted alkyl, more preferably a substituted C2 allcyl;R_t is the moiety Qt-A wherein: Q is a branched or unbranched al ylene, preferably a to C3 allcyl, t=0 or 1 andA is an anionic group selected from the group consisting of OS03 S03', C02', OC02 OP032', OP03H'and OP02', preferably A is an anionic group selected from the group consisting of OS03', S03', C02', and OC02'; preferably R is OS03';R5 is the moiety -CRnRι2-X-Gb-Xc-[(CR9R10)y-O]k-R8 wherein: each X is independently selected from the group consisting of O, S, N-H, or N-R8; and each R8 is independently selected from the group consisting of alkyl, aryl and heteroaryl, said R8 moieties being substituted or unsubstituted, and whether substituted or unsubsituted said Rs moieties having less than 21 carbons; each G is independently selected from the group consisting of CO, S02, SO, PO and P02;R9 and R10 are independently selected from the group consisting of H and C C alkyl; and Rn and R]2 are independently selected from the group consisting of H and alkyl, or when taken together may form a carbonyl; b = 0 or l; c can = 0 or 1, but c must = 0 if b = 0; y is an integer from 1 to 6; k is an integer from 0 to 20; preferably R5 is the moiety -CRnRi2-X-Gb-Xc-R8 wherein: each X is independently selected from the group consisting ofO, S, N-H, or N-R8; and each R8 is independently selected from the group consisting of alkyl, aryl and heteroaryl, said R8 moieties being substituted or unsubstituted, and whether substituted or unsubsituted said R8 moieties having less than 21 carbons; each G is independently selected from the group consisting ofCO, S02, SO, PO and P02;Rn and Rι2 are independently selected from the group consisting of H and alkyl; b = 0 or l; c can = 0 or 1, but c must = 0 if b = 1; more preferably R5 is the moiety -CH2-0-R8 wherein each R8 is independently selected from the group consisting of alkyl, aryl and heteroaryl, said R8 moieties being substituted or unsubstituted, and whether substituted or unsubsituted said R8 moieties having less than 21 carbons; and R6 is H, or an alkyl, aryl or heteroaryl moiety; said moieties being substit...
세정 조성물 중의 이미늄염본 발명은 이미늄 또는 옥사지리디늄 잔기를 포함하는 유기 촉매, 이러한 촉매를 포함하는 세정 조성물 및 이러한 촉매와 세정 제품을 제조하고 사용하는 방법에 관한 것이다. 화학식 1의 유기 촉매. 화학식 1  위의 화학식 1에서, R1은 치환되거나 치환되지 않은 아릴 또는 헤테로아릴기이며, R2는 치환되거나 치환되지 않은 알킬이며, R1과 R2는 이미늄과 함께 환, 바람직하게는 6원 환을 형성하며, R3은 C1 내지 C20 치환된 알킬, 바람직하게는 C1 내지 C12 치환된 알킬, 더욱 바람직하게는 치환된 C2 알킬이며, R4는 잔기 Qt-A(여기서, Q는 분지형 또는 비분지형 알킬렌, 바람직하게는 C1 내지 C3 알킬이며, t는 0 또는 1이며, A는 OSO3-, SO3- , CO2-, OCO2-, OPO3 2-, OPO 3H- 및 OPO2- 로 이루어진 그룹으로부터 선택된 음이온기이며, 바람직하게는 A는 OSO3 -, SO3-, CO2- 및 OCO2-로 이루어진 그룹으로부터 선택된 음이온기이다)이며, 바람직하게는 R4는 OSO3-이며, R5는 -CR11R12-X-Gb-Xc-[(CR9R10 )y-O]k-R8 잔기(여기서, X는 각각 O, S, N-H 및 N-R8로 이루어진 그룹으로부터 독립적으로 선택되며, R8은 치환되거나 치환되지 않으며, 치환되든 치환되지 않든간에 탄소수가 21 미만인 알킬, 아릴 및 헤테로아릴로 이루어진 그룹으로부터 각각 독립적으로 선택되며, G는 각각 CO, SO2, SO, PO 및 PO2로 이루어진 그룹으로부터 독립적으로 선택되며, R9와 R10은 H와 C1 -C4 알킬로 이루어진 그룹으로부터 독립적으로 선택되며, R11과 R12는 H와 알킬로 이루어진 그룹으로부터 독립적으로 선택되거나, 함께 결합하여 카보닐을 형성할 수 있으며, b는 0 또는 1이며, c는 0 또는 1일 수 있으나, b가 0이면 c는 0이며, y는 1 내지 6의 정수이며, k는 0 내지 20의 정수이다)이며, 바람직하게는 R5는 -CR11R12-X-G b-Xc-R8 잔기(여기서, X는 각각 O, S, N-H 또는 N-R8로 이루어진 그룹으로부터 독립적으로 선택되며, R8은 치환되거나 치환되지 않으며, 치환되든 치환되지 않든간에 탄소수가 21 미만인 알킬, 아릴 및 헤테로아릴로 이루어진 그룹으로부터 각각 독립적으로 선택되며, G는 각각 CO, SO2, SO, PO 및 PO2로 이루어진 그룹으로부터 독립적으로 선택되며, R11과 R12는 H와 알킬로 이루어진 그룹으로부터 독립적으로 선택되며, b는 0 또는 1이며, c는 0 또는 1일 수 있으나 b가 1이면 c는 0이다)이며, 더욱 바람직하게는 R5는 -CH2-O-R8 잔기(여기서, R8은 치환되거나 치환되지 않으며, 치환되든 치환되지 않든간에 탄소수가 21 미만인 알킬, 아릴 및 헤테로아릴로 이루어진 그룹으로부터 각각 독립적으로 선택된다)이며, R6은 H, 또는 치환되거나 치환되지 않은 알킬, 아릴 또는 헤테로아릴 잔기이다.