PYRIDINE AND PYRIMIDINE CARBOXYLATE HERBICIDES AND METHODS OF USE THEREOFProvided herein are pyridine and pyrimidine carboxylates and their derivatives, and compositions and methods of use thereof as herbicides.A compound of Formula (I): whereinAr isXi is N or CR6;R is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted phenyl, substituted or unsubstituted benzyl, substituted or unsubstitutedpyridinylmethyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl;Ri, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, halogen, hydroxy, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted haloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted halocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted alkoxy, substituted or unsubstituted haloalkoxy, substituted or unsubstituted alkylsulfanyl, substituted or unsubstituted haloalkylsulfanyl, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted haloalkylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted haloalkylsulfonyl, substituted or unsubstituted alkylsulfonyl(oxy), substituted or unsubstituted haloalkylsulfonyl(oxy), amino, alkylamino, dialkylamino, amido, formyl, 2,2- dimethylhydrazono, methoxyimino, hydroxyimino, alkylcarbonyl, alkoxycarbonyl, nitro, and cyano, or Ri and R2, R2 and R3, R3 and R4 or R4 and R5 together can form a substituted or unsubstituted 5- or 6-membered aliphatic or aromatic ring, containing 0 to 3 heteroatoms selected from the group consisting of O, N, and S;R6 is hydrogen, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, substituted or unsubstituted alkynyl, substituted or unsubstituted alkoxy, substituted or unsubstituted alkylsulfanyl, hydroxy, amino, cyano, or acylamino;Y is selected from the group consisting of hydrogen, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted haloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted alkoxy, substituted or unsubstituted haloalkoxy, substituted or unsubstituted alkylsulfanyl, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted alkylsulfonyl, nitro, and cyano;Z is selected from the group consisting of hydrogen, halogen, alkyl, haloalkyl, alkynyl, alkoxy, haloalkoxy, alkylsulfanyl, amino, nitro, and cyano;with the proviso that when Xi = N, Y is not alkoxy;A compound of Formula (I): whereinAr is Xi is N or CRe;X2 is N or CRi;X3 is N or CR2;X4 is N or CR3;R is hydrogen, substituted or unsubstituted alkyl, phenyl, substituted or unsubstituted benzyl, substituted or unsubstituted pyridinylmethyl, substituted or unsubstituted alkenyl, or substituted or unsubstituted alkynyl;Ri, R2, R3, R4, and R5 are independently selected from the group consisting of hydrogen, halogen, hydroxy, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted haloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted halocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted aryloxy, substituted or unsubstituted alkoxy, substituted or unsubstituted haloalkoxy, substituted or unsubstituted alkylsulfanyl, substituted or unsubstituted haloalkylsulfanyl, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted haloalkylsulfinyl, substituted or unsubstituted alkylsulfonyl, substituted or unsubstituted haloalkylsulfonyl, substituted or unsubstituted alkylsulfonyl(oxy), substituted or unsubstituted haloalkylsulfonyl(oxy), amino, alkylamino, dialkylamino, amido, formyl, 2,2- dimethylhydrazono, methoxyimino, hydroxyimino, alkylcarbonyl, alkoxycarbonyl, nitro, and cyano, or Ri and R2, R2 and R3, R3 and R4 or R* and R5 together can form a substituted or unsubstituted 5- or 6-membered aliphatic or aromatic ring, containing 0 to 3 heteroatoms selected from the group consisting of O, N, and S;R6 is hydrogen, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, substituted or unsubstituted alkynyl, substituted or unsubstituted alkoxy, substituted or unsubstituted alkylsulfanyl, hydroxy, amino, cyano, or acylamino;Y is selected from the group consisting of hydrogen, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted haloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted alkoxy, substituted or unsubstituted haloalkoxy, substituted or unsubstituted alkylsulfanyl, substituted or unsubstituted alkylsulfinyl, substituted or unsubstituted alkylsulfonyl, nitro, and cyano; andZ is selected from the group consisting of hydrogen, halogen, alkyl, haloalkyl, alkynyl, alkoxy, haloalkoxy, alkylsulfan...
피리딘 및 피리미딘 카복실레이트 제초제, 및 이들의 사용 방법피리딘 및 피리미딘 카복실레이트, 이들의 유도체 및 조성물, 및 이들을 제초제로서 사용하는 방법이 본원에 제공된다.화학식 I의 화합물:[화학식 I](식 중,Ar은 이고;X1은 N 또는 CR6이고;R은 수소, 치환 또는 비치환 알킬, 치환 또는 비치환 페닐, 치환 또는 비치환 벤질, 치환 또는 비치환 피리디닐메틸, 치환 또는 비치환 알케닐, 또는 치환 또는 비치환 알키닐이고;R1, R2, R3, R4, 및 R5는 수소, 할로겐, 하이드록시, 치환 또는 비치환 알킬, 치환 또는 비치환 할로알킬, 치환 또는 비치환 알케닐, 치환 또는 비치환 할로알케닐, 치환 또는 비치환 알키닐, 치환 또는 비치환 시클로알킬, 치환 또는 비치환 할로시클로알킬, 치환 또는 비치환 아릴, 치환 또는 비치환 아릴옥시, 치환 또는 비치환 알콕시, 치환 또는 비치환 할로알콕시, 치환 또는 비치환 알킬설파닐, 치환 또는 비치환 할로알킬설파닐, 치환 또는 비치환 알킬설피닐, 치환 또는 비치환 할로알킬설피닐, 치환 또는 비치환 알킬설포닐, 치환 또는 비치환 할로알킬설포닐, 치환 또는 비치환 알킬설포닐(옥시), 치환 또는 비치환 할로알킬설포닐(옥시), 아미노, 알킬아미노, 디알킬아미노, 아미도, 포르밀, 2,2-디메틸히드라조노, 메톡시이미노, 하이드록시이미노, 알킬카보닐, 알콕시카보닐, 니트로, 및 시아노로 이루어진 군으로부터 독립적으로 선택되거나, R1과 R2, R2와 R3, R3과 R4, 또는 R4와 R5는 함께, O, N, 및 S로 이루어진 군으로부터 선택되는 0 내지 3개의 헤테로원자를 함유하는 치환 또는 비치환 5원 또는 6원 지방족 또는 방향족 고리를 형성할 수 있고;R6은 수소, 할로겐, 치환 또는 비치환 알킬, 치환 또는 비치환 할로알킬, 치환 또는 비치환 알키닐, 치환 또는 비치환 알콕시, 치환 또는 비치환 알킬설파닐, 하이드록시, 아미노, 시아노, 또는 아실아미노이고;Y는 수소, 할로겐, 치환 또는 비치환 알킬, 치환 또는 비치환 할로알킬, 치환 또는 비치환 알케닐, 치환 또는 비치환 할로알케닐, 치환 또는 비치환 알키닐, 치환 또는 비치환 알콕시, 치환 또는 비치환 할로알콕시, 치환 또는 비치환 알킬설파닐, 치환 또는 비치환 알킬설피닐, 치환 또는 비치환 알킬설포닐, 니트로, 및 시아노로 이루어진 군으로부터 선택되고;Z는 수소, 할로겐, 알킬, 할로알킬, 알키닐, 알콕시, 할로알콕시, 알킬설파닐, 아미노, 니트로, 및 시아노로 이루어진 군으로부터 선택되고;단, X1 = N일 경우, Y는 알콕시가 아니며;화학식 I의 화합물은이 아님).