HETEROCYCLENE DERIVATIVES AS PEST CONTROL AGENTSThe invention relates to novel compounds of formula (I), wherein X, R1, R2, R3, and n have the meanings indicated in the description, to the use thereof as acaricides and/or insecticides for controlling animal pests, and to methods and intermediate products for the production thereof.The compound of formula (i)whereinr1for (c1-c6) alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, (c1-c6) alkoxy-(c1-c6) alkyl, (c1-c6) halogenated alkyl, (c2-c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) alkynyl, (c2-c6) halo alkynyl or (c3-c8) naphthenic base,r2for hydrogen, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, (c1-c6) alkane oxygroup-(c1-c6) alkyl, (c1-c6) halogenated alkoxy-(c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) alkenyloxy group-(c1-c6) alkyl, (c2-c6) haloalkenyloxy-(c1-c6) alkyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c2-c6) alkynyl, (c2-c6) alkynyloxy group-(c1-c6) alkyl, (c2-c6) halogenated alkynyloxy group-(c1-c6) alkyl, (c2-c6) halo alkynyl, (c2-c6) cyanogen base alkynyl, (c3-c8) naphthenic base, (c3-c8) naphthenic base-(c3-c8) naphthenic base, (c1-c6) alkyl-(c3-c8) naphthenic base, halogenated (c3-c8) naphthenic base, cyano (c3-c8) naphthenic base, (c1-c6) alkylthio group-(c1-c6) alkyl, (c1-c6) halogenated alkylthio-(c1- c6) alkyl, (c1-c6) alkyl sulphinyl-(c1-c6) alkyl, (c1-c6) alkylsulfinyl-(c1-c6) alkyl, (c1- c6) alkyl sulphonyl-(c1-c6) alkyl, (c1-c6) halogenated alkyl sulfonyl-(c1-c6) alkyl, (c1-c6) alkyl-carbonyl-(c1- c6) alkyl, (c1-c6) halogenated alkyl carbonyl-(c1-c6) alkyl, (c1-c6) alkoxy carbonyl-(c1-c6) alkyl or (c1-c6) halogen for alkoxy carbonyl-(c1-c6) alkyl,r3for polysubstituted (c being optionally mono-substituted or identical or differently3-c8) naphthenic base, wherein in each case may be used the substituent group of energy are as follows: (c3-c8) naphthenic base, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) alkoxy, (c1-c6) halogenated alkoxy, amino carbonyl, aminothiocarbonyl, halogen or cyano,x is the heteroaromatic 9 yuan or 12 yuan condensed bicyclic or tricyclic ring systems selected from q1 to q18r4for hydrogen, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c1-c6) cyanoalkyl, (c1-c6) hydroxy alkyl, (c1-c6) alkane oxygroup-(c1-c6) alkyl, (c1-c6) halogenated alkoxy-(c1-c6) alkyl, (c2-c6) alkenyl, (c2-c6) alkenyloxy group-(c1-c6) alkyl, (c2-c6) haloalkenyloxy-(c1-c6) alkyl, (c2-c6) halogenated alkenyl, (c2-c6) cyano alkenyl, (c2-c6) alkynyl, (c2-c6) halo alkynyl or (c3-c8) naphthenic base,r5、r6it independently is hydrogen, cyano, halogen, (c1-c6) alkyl, (c1-c6) halogenated alkyl, (c2-c6) alkenyl, (c2-c6) halogenated alkenyl, (c2-c6) alkynyl, (c2-c6) halo alkynyl, (c3-c8) naphthenic base, (c3-c8) naphthenic base-(c3-c8) naphthenic base, (c1- c6) alkyl-(c3-c8) naphthenic base, (c1-c6) halogenated alkyl-(c3-c8) naphthenic base, cyano-(c3-c8) naphthenic base, halogenated-(c3- c8) naphthenic base, (c1-c6) alkoxy, (c1-c6) halogenated alkoxy, (c1-c6) alkoximino, (c1-c6) halogenated alkoxy imino group, (c1-c6) alkylthio group, (c1-c6) halogenated alkylthio, (c1-c6) alkyl sulphinyl, (c1-c6) halogenated alkyl sulfenyl base, (c1-c6) alkyl sulphonyl, (c1-c6) halogenated alkyl sulfonyl, (c1-c6) alkyl sulphonyl oxygroup, (c1-c6) halogenated alkyl sulfonyl oxygroup, (c1-c6) alkyl-carbonyl, (c1-c6) halogenated alkyl carbonyl, amino carbonyl, (c1-c6) alkyl amino-carbonyl, two- (c1-c6) alkyl-aminocarbonyl, (c1-c6) alkyl sulfonyl-amino, (c1-c6) alkyl amino, two-(c1-c6) alkyl amino, ammonia base sulfonyl, (c1-c6) alkyl amino sulfonyl or two-(c1-c6) alkyl amino sulfonyl,n is 0,1 or 2.
해충 방제제로서의 헤테로사이클 유도체본 발명은 화학식 (I)의 신규 화합물, 동물 해충을 방제하기 위한 살응애제 및/또는 살충제로서의 그의 용도, 및 그의 제조를 위한 방법 및 중간체에 관한 것이다:[이미지] 상기 식에서, X, R1, R2, R3 및 n은 각각 상기 정의된 바와 같다.화학식 (I)의 화합물:[이미지]상기 식에서,R1은 (C1-C6)알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐 또는 (C3-C8)사이클로알킬이고,R2는 수소, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)알키닐옥시-(C1-C6)알킬, (C2-C6)할로알키닐옥시-(C1-C6)알킬, (C2-C6)할로알키닐, (C2-C6)시아노알키닐, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, 할로(C3-C8)사이클로알킬, 시아노(C3-C8)사이클로알킬, (C1-C6)알킬티오-(C1-C6)알킬, (C1-C6)할로알킬티오-(C1-C6)알킬, (C1-C6)알킬설피닐-(C1-C6)알킬, (C1-C6)할로알킬설피닐-(C1-C6)알킬, (C1-C6)알킬설포닐-(C1-C6)알킬, (C1-C6)할로알킬설포닐-(C1-C6)알킬, (C1-C6)알킬카보닐-(C1-C6)알킬, (C1-C6)할로알킬카보닐-(C1-C6)알킬, (C1-C6)알콕시카보닐-(C1-C6)알킬 또는 (C1-C6)할로알콕시카보닐-(C1-C6)알킬이고, R3은 임의로 동일하거나 상이하게 일- 또는 다치환된 (C3-C8)사이클로알킬이고, 여기서 각 경우 가능한 치환체는 (C3-C8)사이클로알킬, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)알콕시, (C1-C6)할로알콕시, 아미노카보닐, 아미노티오카보닐, 할로겐 또는 시아노이고,X는 Q1 내지 Q18 그룹으로부터의 헤테로방향족 9-원 또는 12-원 융합 비사이클릭 또는 트리사이클릭 환 시스템이고:[이미지][이미지][이미지]R4는 수소, (C1-C6)알킬, (C1-C6)할로알킬, (C1-C6)시아노알킬, (C1-C6)하이드록시알킬, (C1-C6)알콕시-(C1-C6)알킬, (C1-C6)할로알콕시-(C1-C6)알킬, (C2-C6)알케닐, (C2-C6)알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐옥시-(C1-C6)알킬, (C2-C6)할로알케닐, (C2-C6)시아노알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐 또는 (C3-C8)사이클로알킬이고, R5, R6은 독립적으로 수소, 시아노, 할로겐, (C1-C6)알킬, (C1-C6)할로알킬, (C2-C6)알케닐, (C2-C6)할로알케닐, (C2-C6)알키닐, (C2-C6)할로알키닐, (C3-C8)사이클로알킬, (C3-C8)사이클로알킬-(C3-C8)사이클로알킬, (C1-C6)알킬-(C3-C8)사이클로알킬, (C1-C6)할로알킬-(C3-C8)사이클로알킬, 시아노-(C3-C8)사이클로알킬, 할로-(C3-C8)사이클로알킬, (C1-C6)알콕시, (C1-C6)할로알콕시, (C1-C6)알콕시이미노, (C1-C6)할로알콕시이미노 (C1-C6)알킬티오, (C1-C6)할로알킬티오, (C1-C6)알킬설피닐, (C1-C6)할로알킬설피닐, (C1-C6)알킬설포닐, (C1-C6)할로알킬설포닐, (C1-C6)알킬설포닐옥시, (C1-C6)할로알킬설포닐옥시, (C1-C6)알킬카보닐, (C1-C6)할로알킬카보닐, 아미노카보닐, (C1-C6)알킬아미노카보닐, 디-(C1-C6)알킬-아미노카보닐, (C1-C6)알킬설포닐아미노, (C1-C6)알킬아미노, 디-(C1-C6)알킬아미노, 아미노설포닐, (C1-C6)알킬아미노설포닐 또는 디-(C1-C6)알킬아미노설포닐이고,n은 0, 1 또는 2이다.