Selective herbicides on basis of n-aryl-trizoline (thio) onesThe invention relates to novel herbicidal synergistic active compound combinations comprising on the one hand known N-aryl-triazolin(ethi)ones and on the other hand known herbicidally active compounds and/or compounds which improve crop plant compatibility and which can be used with particularly good results for the selective control of weeds in various crops of useful plants.A composition is characterized in that said composition comprises the active substance combinations of effective dose, contains in this mixture(a) n-aryl-triazoline (sulphur) ketone of at least a general formula (i) wherein q 1represent oxygen or sulphur, r 1represent the selectively alkyl with 1-5 carbon atom of halogen replacement, r 2represent the selectively alkyl with 1-5 carbon atom of halogen replacement, r 3represent hydrogen or halogen, r 4represent cyano group, thiocarbamoyl or halogen, and r 5represent nitro, cyano group, carboxyl, carbamoyl, thiocarbamoyl, hydroxyl, sulfydryl, amino, hydroxylamino, amino-sulfonyl, halogen, the representative separately selectively by cyano group-, hydroxyl-, c 1-c 4-alkoxyl-, c 1-c 4-alkyl-carbonyl-and/or c 1-c 4the alkyl that contains 1-6 carbon atom separately of-alkoxy carbonyl-replacement, alkoxyl, alkylthio group, alkyl sulphinyl, alkyl sulphonyl, alkyl-carbonyl, alkoxy carbonyl or alkyl amino, representative separately selectively by cyano group-, carboxyl-, halogen-and/or c 1-c 4the alkenyl that contains 2-6 carbon atom separately of-alkoxy carbonyl-replacement; alkynyl; alkenyloxy or alkynyloxy group, each comfortable moieties that representative is selectively replaced by halogen separately contains the alkyl-carbonyl-amino of 1-6 carbon atom, alkoxycarbonyl amino; alkyl sulfonyl-amino; n, n-dialkyl group sulfuryl amino or n-alkyl-carbonyl-n-alkyl sulfonyl-amino, or the representative separately selectively by cyano group-; halogen-, c 1-c 4-alkyl-, c 1-c 4-haloalkyl-, c 1-c 4-alkoxyl-or c 1-c 4the comfortable moieties of each of-halogenated alkoxy-replacement contains the n-phenylcarbonyl group-n-alkyl sulfonyl-amino of 1-6 carbon atom; n-pyridine radicals carbonyl-n-alkyl sulfonyl-amino; n-furyl carbonyl-n-alkyl sulfonyl-amino or n-thienyl carbonyl-n-alkyl sulfonyl-amino (' reactive compound of group 1 ')and(b) be selected from least a compound of second group of weed killer herbicide, wherein second group of weed killer herbicide comprises following reactive compound:2 - chloro-n-(ethoxymethyl)-n-(2 - ethyl-6 - methyl - phenyl) - acetamide (dimethachlor amine), 5 - (2 - chloro -4 - (trifluoromethyl) - phenoxy) -2 - nitro - acid salt (of trifluoromethyl carboxymethyl ether), 2 - chloro-6 - nitro-3 - phenoxy - aniline (aclonifen), 2 - chloro-n-(methoxymethyl) - n-(2,6 - diethyl - phenyl) - acetamide (alachlor), n-ethyl-n'-isopropyl-6 - (methylthio) -1,3,5 - triazine-2 ,4 - diamine (ametryn), 4 - amino-n-(1,1 - dimethyl - ethyl) - 4,5 - dihydro-3 - (1 - methyl - ethyl) -5 - oxo-1h-1, 2,4 - triazol-1 - carboxamide (amicarbazone), n-(4,6 - dimethoxy - pyrimidin-2 - yl)-n'-(n-methyl-n-methyl- - sulfonyl - sulfamoyl) - urea (acid-ethyl), 1h-1, 2,4 - triazol-3 - amine (amitrole), 6 - chloro-4 - ethyl-2 - isopropyl-1 ,3,5 - triazine (atrazine), n-(4,6 - dimethoxyphenyl yl - pyrimidin-2 - yl)-n'-[1 - methyl - 4 - (2 - methyl-2h-tetrazol-5 - yl)-1h-pyrazol-5 -  group - sulfonyl] - urea (tetrazol-ethyl), 2 - [2,4 - dichloro-5 - (2 - propynyloxy) - phenyl] - 5,6,7,8 - tetrahydro-1 ,2,4 - triazolo - [4,3-a] - pyridine -3 (2h) - one (yl propargyl piperidine grass), n-benzyl-2 - (4 - fluoro-3 - (trifluoromethyl) - phenoxy) butyramide (beflubutamid), 4 - chloro-2 - oxo -3 (2h) - benzo-thiazole acetic acid (benazolin), n-d yl-n-ethyl-2 ,6 - dinitro-4 - (trifluoromethyl) - aniline (b d f ling), n-(4,6 - dimethoxyphenyl oxy - pyrimidin-2 - yl)-n'-(2 - methoxycarbonyl - phenyl methyl sulfonyl) - urea (bensulfuron yellow long), 2 - [2 - [4 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2h) - pyrimidin piperidinyl) phenoxy] methyl]-5 - ethyl - phenoxy - propionate (benzfendizone), 3 - (2 - chloro-4 - methylsulphonyl - benzoyl) -4 - phenylthio - bicyclo - [3.2.1] - oct-3 - ene - 2 - one (benzobicyclon), n-benzoyl-n-(3,4 - dichloro - phenyl)-dl-alanine ethyl (new yan spirit) 3 - isopropyl-1h-2, 1,3 - benzothiadiazin -4 (3h) - one (herbicides pine), 5 - (2,4 - dichloro - phenoxy) -2 - nitro - benzoate (carboxymethyl nitrofen), 2,6 - bis - (4,6 - dimethoxy - pyrimidin-2 - yl - oxy) - benzoate (bispyribac-sodium), 2 - bromo-3 ,3 - dimethyl-n-(1 - methyl-1 - phenyl - ethyl) - butyramide (bromo butyryl alachlor), 0 - (2,4 - nitro - phenyl) 3,5 - dibromo-4 - hydroxy - benzaldehyde oxime (bromophenol oxime), 3,5 - dibromo-4 - hydroxy - benzonitrile (bromoxynil), n-butoxy - methyl - 2 - chloro-n-(2,6 - diethyl - phenyl) - acetamide (butachlor), [1,1 - dimethyl-2 - oxo-2 - (2 - propenyl oxy)] - ethyl 2 - chloro -5 - (3,6 - dihydro-3 - methyl-2 ,6 - dioxo-4 - (trifluoromethyl) -1 (2h) - pyrimidinyl) - benzoic acid ester (butafenacil-allyl), 2 - (1 - ethoxyimino - propyl) -3 - hydroxy-5 - [2,4,6 - trimethyl-3 - (1 - oxo - butyl) - phenyl]-2 - cyclohexen-1 - one (butoxy-ring ketone), s-ethyl bis - (2 - methyl - propyl) - thio carbamate (gerbera enemy), n, n-diethyl -3 - (2,4,6 - trimethyl - phenylsulfonyl)-1h-1, 2,4 - triazol-1 - carboxamide (phenone yl), 2 - [1 -...
Ｎ-아릴 트리아졸린(티)온을 기본으로 한 선택적 제초제본 발명은, 한편으로 공지된 N-아릴-트리아졸린(티)온 및 다른 한편으로 공지된 제초활성 화합물 및/또는 작물과의 상용성(compatibility)을 개선시키는 화합물을 함유하며 사용시 유용한 각종 작물중에서 잡초를 선택적으로 방제하는데 특히 우수한 결과를 나타낼 수 있는 상승적 제초 활성 배합물에 관한 것이다.(a) 적어도 하나의 하기 일반식 (I)의 N-아릴-트리아졸린(티)온("그룹 1의 활성 화합물") 및 (b) 2-클로로-N-(에톡시메틸)-N-(2-에틸-6-메틸-페닐)-아세트아미드(아세토클로르), 5-(2-클로로-4-트리플루오로메틸-페녹시)-2-니트로-벤조산 소듐염(아시플루오르펜-소듐), 2-클로로-6-니트로-3-페녹시-벤젠아민(아클로니펜), 2-클로로-N-(메톡시메틸)-N-(2,6-디에틸-페닐)-아세트아미드(알라클로르), N-에틸-N'-i-프로필-6-메틸티오-1,3,5-트리아진-2,4-디아민(아메트린), 4-아미노-N-(1,1-디메틸-에틸)-4,5-디하이드로-3-(1-메틸-에틸)-5-옥소-1H-1,2,4-트리아졸-1-카복사미드(아미카바존), N-(4,6-디메톡시-피리미딘-2-일)-N'-(N-메틸-N-메틸설포닐-설파모일)-우레아(아미도설푸론), 1H-1,2,4-트리아졸-3-아민(아미트롤), 6-클로로-4-에틸아미노-2-이소프로필아미노-1,3,5-트리아진(아트라진), N-(4,6-디메톡시-피리미딘-2-일)-N'-[1-메틸-4-(2-메틸-2H-테트라졸-5-일)-1H-피라졸-5-일-설포닐]-우레아(아짐설푸론), 2-[2,4-디클로로-5-(2-프로피닐옥시)-페닐]-5,6,7,8-테트라하이드로-1,2,4-트리아졸로-[4,3,a]-피리딘-3(2H)-온(아자페니딘), N-벤질-2-(4-플루오로-3-트리플루오로메틸-페녹시)-부탄아미드(베플루부타미드), 4-클로로-2-옥소-3(2H)-벤조티아졸아세트산(베나졸린), N-부틸-N-에틸-2,6-디니트로-4-트리플루오로메틸-벤젠아민(벤플루랄린), N-(4,6-디메톡시-피리미딘-2-일)-N'-(2-메톡시카보닐-페닐메틸설포닐)-우레아(벤설푸론), 메틸 2-[2-[4-(3,6-디하이드로-3-메틸-2,6-디옥소-4-트리플루오로메틸-1(2H)-피리미디닐)페녹시]메틸]-5-에틸-페녹시-프로파노에이트(벤즈펜디존), 3-(2-클로로-4-메틸설포닐-벤조일)-4-페닐티오-바이사이클로-[3.2.1]-옥트-3-엔-2-온(벤조바이사이클론), 에틸 N-벤조일-N-(3,4-디클로로-페닐)-DL-알라니네이트(벤조일프로프-에틸), 3-i-프로필-1H-2,1,3-벤조티아디아진-4(3H)-온(벤타존), 메틸 5-(2,4-디클로로-페녹시)-2-니트로-벤조에이트(비페녹스), 2,6-비스-(4,6-디메톡시 -피리미딘-2-일-옥시)-벤조산 소듐염(비스피리박-소듐), 2-브로모-3,3-디메틸-N-(1-메틸-1-페닐-에틸)-부탄아미드(브로모부타이드), O-(2,4-디니트로-페닐) 3,5-디브로모-4-하이드록시-벤즈알데하이드-옥심(브로모페녹심), 3,5-디브로모-4-하이드록시-벤조니트릴(브로목시닐), N-부톡시메틸-2-클로로-N-(2,6-디에틸-페닐)-아세트아미드(부타클로르), [1,1-디메틸-2-옥소-2-(2-프로페닐옥시)]-에틸 2-클로로-5-(3,6-디하이드로-3-메틸-2,6-디옥소-4-트리플루오로메틸-1(2H)-피리미디닐)-벤조에이트(부타페나실-알릴), 2-(1-에톡스이미노-프로필)-3-하이드록시-5-[2,4,6-트리메틸-3-(1-옥소-부틸)-페닐]-2-사이클로헥센-1-온(부트록시딤), S-에틸 비스-(2-메틸 -프로필)-티오카바메이트(부틸레이트), N,N-디에틸-3-(2,4,6-트리메틸-페닐-설포닐)-1H-1,2,4-트리아졸-1-카복사미드(카펜스트롤), 2-[1-[(3-클로로-2-프로페닐)-옥시-이미노]-프로필]-3-하이드록시-5-(테트라하이드로-2H-피란-4-일)-2-사이클로헥센-1-온(칼록시딤, 테프랄록시딤), 2-(4-클로로-2-플루오로-5-(2-클로로-2-에톡시카보닐-에틸)-페닐)-4-디플루오로메틸-5-메틸-2,4-디하이드로-3H-1,2,4-트리아졸-3-온(카펜트라존-에틸), 2,4-디클로로-1-(3-메톡시-4-니트로-페녹시)-벤젠(클로메톡시펜), 3-아미노-2,5-디클로로-벤조산(클로람벤), N-(4-클로로-6-메톡시-피리미딘-2-일)-N'-(2-에톡시카보닐-페닐설포닐)-우레아(클로리무론-에틸), 1,3,5-트리클로로-2-(4-니트로-페녹시)-벤젠(클로르니트로펜), N-(4-메톡시-6-메틸-1,3,5-트리아진-2-일)-N'-(2-클로로-페닐설포닐)-우레아(클로르설푸론), N'-(3-클로로-4-메틸 -페닐)-N,N-디메틸-우레아(클로르톨루론), 에틸 2-클로로-3-[2-클로로-5-(1,3,4,5,6,7-헥사하이드로-1,3-디옥소-2H-이소인돌-2-일)-페닐]-2-프로파노에이트(시니돈-에틸), N-(4,6-디메톡시-1,3,5-트리아진-2-일)-N'-(2-(2-메톡시-에톡시)-페닐설포닐)-우레아(시노설푸론), 2-[1-[2-(4-클로로-페녹시)-프로폭시아미노]부틸]-5-(테트라하이드로-2H-티오피란-3-일)-1,3-사이클로헥산디온(클레폭시딤), (E,E)-(+)-2-[1-[[(3-클로로-2-프로페닐)-옥시]-이미노]-프로필]-5-[2-(에틸티오)-프로필]-3-하이드록시-2-사이클로헥센-1-온(클레토딤), 프로프-2-이닐 (R)-2-[4-(5-클로로-3-플루오로-피리딘-2-일-옥시)-페녹시]-프로파노에이트(클로디나폽-프로파길), 3,6-디클로로-피리딘-2-카복실산(클로피랄리드), 메틸 3-클로로-2-[(5-에톡시-7-플루오로[1,2,4]트리아졸로[1,5-c]피리미딘-2-일-설포닐)-아미노]-벤조에이트(클로란설람-메틸), 2-클로로-4-에틸아미노-6-(1-시아노-1-메틸-에틸아미노)-1,3,5 -트리아진(시아나진), N-(4,6-디메톡시-피리미딘-2-일)-N'-(2-사이클로프로필카보닐-페닐설포닐)-우레아(사이클로설파무론), 2-(1-에톡스이미노부틸)-3-하이드록시-5-(테트라하이드로-2H-티오피란-3-일)-2-사이클로헥센-1-온(사이클록시딤), 부틸 (R)-2-[4-(4-시아노-2-플루오로-페녹시)-페녹시]-프로파노에이트(사이할로폽-부틸), 2,4-디클로로-페녹시아세트산(2,4-D), 3,6-디클로로-2-메톡시-벤조산(디캄바), (R)-2-(2,4-디클로로-페녹시)프로판산(디클로르프로프-P), 메틸-2-[4-(2,4-디클로로-페녹시)-페녹시]-프로파노에이트(디클로폽-메틸), N-(2,6-디클로로-페닐)-5-에톡시-7-플루오로-[1,2,4]-트리아졸로-[1,5-c]-피리미딘-2-설폰아미드(디클로설람), 1,2-디메틸-3,5-디페닐-1H-피라졸륨 메틸설페이트(디펜조쿠아트), N-(2,4-디플루오로-페닐)-2-(3-트리플루오로메틸-페녹시)-피리딘-3-카복사미드(디플루페니칸), 2-[1-[(3,5-디플루오로-페닐)-아미노-카보닐-하이드라조노]-에틸]-피리딘-3-카복실산(디플루펜조피르), S-(1-메틸-1-페닐-에틸) 1-피페리딘-카보티오에이트(디메피페레이트), 2-클로로-N-(2,4-디메틸-3-티에닐)-N-(2-메톡시-1-메틸-에틸)-아세트아미드 (디메텐아미드), 2-아미노-4-(1-플루오로-1-메틸-에틸)-6-(1-메틸-2-(3,5-디메틸-페녹시)-에틸아미노)-1,3,5-트리아진(디멕시플람), N3,N3-디에틸-2,4-디니트로-6-트리플루오로메틸-1,3-디아미노-벤젠(디니트라민), 6,7-디하이드로-디피리도[1,2-a:2',1'-c]피라진디이움(디쿠아트), S,S-디메틸 2-디플루오로메틸-4-i-부틸-6-트리플루오로메틸-피리딘-3,5-디카보티오에이트(디티오피르), N'-(3,4-디클로로-페닐)-N,N-디메틸-우레아(디우론), 2-[2-(3-클로로-페닐)-옥시라닐메틸]-2-에틸-1H-인덴-1,3(2H)-디온(에프로포단), S-에틸 디프로필티오카바메이트(EPTC), S-(페닐메틸) N-에틸-N-(1,2-디메틸-프로필)-티오카바메이트(에스프로카브), N-에틸-N-(2-메틸-2-프로페닐)-2,6-디니트로-4-트리플루오로메틸-벤젠아민(에탈플루랄린), 2-에톡시-1-메틸-2-옥소에틸 (S)-2-클로로-5-(2-클로로-4-트리플루오로메틸-페녹시)-벤조에이트(에톡시펜), N-(4,6-디메톡시-피리미딘-2-일)-N'-(2-에톡시-페녹시설포닐)-우레아(에톡시설푸론), 에틸 (R)-2-[4-(6-클로로-벤족사졸-2-일-옥시)-페녹시]-프로파노에이트(페녹사프로폽-(P)-에틸), 4-(2-클로로-페닐)-N-사이클로헥실-N-에틸-4,5-디하이드로-5-옥소-1H-테트라졸-1-카복사미드(펜트라자미드), 이소프로필 N-벤조일-N-(3-클로로-4-플루오로-페닐)-DL-알라니네이트(플람프로프-이소프로필), 이소프로필 N-벤조일-N-(3-클로로-4-플루오로-페닐)-L-알라니네이트(플람프로프-이소프로필-L), 메틸 N-벤조일-N-(3-클로로-4-플루오로-페녹시)-DL-알라니네이트(플람프로프-메틸), N-(2,6-디플루오로-페닐)-8-플루오로-5-메톡시-[1,2,4]-트리아졸로-[1,5-c]-피리미딘-2-설폰아미드(플로라설람), 부틸 (R)-2-[4-(5-트리플루오로메틸-피리딘-2-일-옥시)-페녹시]-프로파노에이트(플루아지폽, -부틸, -P-부틸), i-프로필 5-(4-브로모-1-메틸-5-트리플루오로메틸-1H-피라졸-3-일)-2-클로로-4-플루오로-벤조에이트(플루아졸레이트), N-(4-플루오로-페닐)-N-i-프로필-2-(5-트리플루오로메틸-1,3,4-티아디아졸-2-일-옥시)-아세트아미드(플루페나세트), N-(2,6-디플루오로-페닐)-5-메틸-1,2,4-트리아졸로[1,5-a]-피리미딘-2-설폰아미드(플루메트설람), 펜틸 [2-클로로-4-플루오로-5-(1,3,4,5,6,7-헥사하이드로-1,3-디옥소-2H-이소인돌-2-일)-페녹시]-아세테이트(플루미클로락-펜틸), 2-[7-플루오로-3,4-디하이드로-3-옥소-4-(2-프로피닐)-2H-1,4-벤족사진-6-일]-4,5,6,7-테트라하이드로-1H-이소인돌-1,3-디온(플루미옥사진), 2-[4-클로로-2-플루오로-5-[(1-메틸-2-프로피닐)-옥시]-페닐]-4,5,6,7-테트라하이드로-1H-이소인돌-1,3(2H)-디온(플루미프로핀), 에톡시카보닐메틸 5-(2-클로로-4-트리플루오로메틸-페녹시)-2-니트로-벤조에이트(플루오로글리코펜-에틸), 1-(4-클로로-3-(2,2,3,3,3-펜타플루오로-프로폭시메틸)-페닐)-5-페닐-1H-1,2,4-트리아졸-3-카복사미드(플루폭삼), 1-이소프로필-2-클로로-5-(3,6-디하이드로-3-메틸-2,6-디옥소-4-트리플루오로메틸-1(2H)-피리미딜)-벤조에이트(플루프로파실), N-(4,6-디메톡시-피리미딘-2-일)-N'-(3-메톡시카보닐-6-트리...