Pesticidal Mixtures Comprising A Pyrazole CompoundPesticidal mixtures comprising as active compounds1) at least one pyrazole compound A of formula I: wherein the variables are as defined in the specification, and 2) at least one further compound B selected from 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4H-isoxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-isoxazolidin-4-yl]-2-methyl-benzamide; 4-[(5S)-5-(3,5-dichloro-4-fluoro-phenyl)-5-(trifluoromethyl)-4H-isoxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-isoxazolidin-4-yl]-2-methyl-benzamide; N-[4-Chloro-3-[[(phenylmethyl)-amino]-carbonyl]-phenyl]-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)-1H-pyrazole-5-carboxamide; N-[4-chloro-3-(cyclopropylcarbamoyl)phenyl]-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)pyrazole-3-carboxamide; N-[4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl]-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)pyrazole-3-carboxamide; 2-chloro-N-(1-cyanocy-clopropyl)-5-[1-[2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)pyrazol-3-yl]pyrazol-4-yl]benzamide; 2-(3-ethylsulfonyl-2-pyridyl)-3-methyl-6-(trifluoromethyl)imidazo[4,5-b]pyridine, 2-(3-ethylsulfonyl-2-pyridyl)-5-(trifluoromethylsulfonyl)-1,3-benzoxazole; spiropidion, acynonapyr, and benzpyrimoxan; methods and use of these mixtures for combating invertebrate pests such as insects, arachnids or nematodes in and on plants, and for protecting such plants being infested with pests, especially also for protecting plant propagation material as like seeds. A pesticidal mixture comprising as active components 1) at least one pyrazole compound A of formula I: whereinR1 is H, CH3, or C2H5;R2 is CH3,R3 is CH3, CH(CH3)2, CF3, CHFCH3, or 1-CN-c-C3H4;R4 is CH3; orR3 and R4 may together form CH2CH2CF2CH2CH2; and2) at least one further compound B selected from the group consisting ofB1) an isoxazoline selected from the group consisting of a) 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4H-isoxazol-3-yl]-N-[(4R)-2-ethyl-3-oxo-isoxazolidin- 4-yl]-2-methyl-benzamide, and b) 4-[(5S)-5-(3,5-dichloro-4-fluoro-phenyl)-5-(trifluoromethyl)-4H-isoxazol-31-yl]-N-[(4R)-2-ethyl-3-oxo-isoxazolidin-4-yl]-2-methyl- benzamide;B2) a carboxamide selected from the group consisting of a) N-[4-Chloro-3-[[(phenylmethyl)-amino]-carbonyl]-phenyl]-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)-4- (trifluoromethyl)-1H-pyrazole-5-carboxamide; b) N-[4-chloro-3-(cyclopropylcarbamoyl)phenyl]-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)pyrazole-3- carboxamide; c) N-[4-chloro-3-[(1-cyanocyclopropyl)carb-amoyl]phenyl]-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)pyrazole-3-carb-oxamide; and d) 2- chloro-N-(1-cyanocyclopropyl)-5-[1-[2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoromethyl)pyrazol-3-yl]pyrazol-4-yl]benzamide;B3) a pyridylsulfone selected from the group consisting of a) 2-(3-ethylsulfonyl-2-pyridyl)-3-methyl-6-(trifluoromethypimidazo[4,5-b]pyridine, and b) 2-(3- thylsulfonyl-2-pyridyl)-5-(trifluoromethylsulfonyl)-1,3-benzoxazole;B4) Spiropidion;B5) Acynonapyr; andB6) Benzpyrimoxan;wherein component 1) and component 2) are present in a weight ratio of from 1000:1 to 1:1000.
피라졸 화합물을 포함하는 살충 혼합물활성 화합물로서 1) 1종 이상의 화학식 I의 피라졸 화합물 A: 여기서 변수는 명세서에 정의된 바와 같고, 2) 4-[5-(3,5-디클로로페닐)로부터 선택된 1종 이상의 추가 화합물 B를 포함하는 살충 혼합물 -5-(트리플루오로메틸)-4H-이속사졸-3-일]-N-[(4R)-2-에틸-3-옥소-이속사졸리딘-4-일]-2-메틸-벤즈아미드; 4-[(5S)-5-(3,5-디클로로-4-플루오로-페닐)-5-(트리플루오로메틸)-4H-이속사졸-3-일]-N-[(4R)-2-에틸-3 -옥소-이속사졸리딘-4-일]-2-메틸-벤즈아미드; N-[4-클로로-3-[[(페닐메틸)-아미노]-카르보닐]-페닐]-1-메틸-3-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)- 1H-피라졸-5-카르복사미드; N-[4-클로로-3-(시클로프로필카르바모일)페닐]-2-메틸-5-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)피라졸-3-카르복사미드; N-[4-클로로-3-[(1-시아노시클로프로필)카르바모일]페닐]-2-메틸-5-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)피라졸-3-카르복사미드 ; 2-클로로-N-(1-시아노시클로프로필)-5-[1-[2-메틸-5-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)피라졸-3-일 ]피라졸-4-일]벤즈아미드; 2-(3-에틸술포닐-2-피리딜)-3-메틸-6-(트리플루오로메틸)이미다조[4,5-b]피리딘, 2-(3-에틸술포닐-2-피리딜)-5-(트리플루오로메틸술포닐)-1 ,3-벤족사졸; 스피로피디온, 아시노나피르, 및 벤즈피리목산; 식물 내부 및 위의 곤충, 거미류 또는 선충류와 같은 무척추동물 해충을 퇴치하고, 해충에 감염된 식물을 보호하기 위한, 특히 종자와 같은 식물 번식 물질을 보호하기 위한 방법 및 이들 혼합물의 용도.활성 성분으로서 1) 화학식 I의 하나 이상의 피라졸 화합물 A를 포함하는 살충 혼합물: 상기 식에서, R1은 H, CH3, 또는 C2H5이고, R2는 CH3이고, R3은 CH3, CH(CH3)2, CF3, CHFCH3, 또는 1-CN이다. -c-C3H4;R4는 CH3이고; 또는R3 및 R4는 함께 CH2CH2CF2CH2CH2를 형성할 수 있고; 및2) B1) a) 4-[5-(3,5-디클로로페닐)-5-(트리플루오로메틸)-4H-이속사졸-3- 일]-N-[(4R)-2-에틸-3-옥소-이속사졸리딘-4-일]-2-메틸-벤즈아미드, 및 b) 4-[(5S)-5-(3,5-디클로로- 4-플루오로-페닐)-5-(트리플루오로메틸)-4H-이속사졸-31-일]-N-[(4R)-2-에틸-3-옥소-이속사졸리딘-4-일]-2-메틸-벤즈아미드; B2) a) N-[4-클로로-3-[[(페닐메틸)-아미노]-카르보닐]-페닐]-1-메틸-3-(1,1,2,2 ,2-펜타플루오로에틸)-4-(트리플루오로메틸)-1H-피라졸-5-카르복사미드; b) N-[4-클로로-3-(시클로프로필카르바모일)페닐]-2-메틸-5-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)피라졸-3-카르복사미드; c) N-[4-클로로-3-[(1-시아노시클로프로필)카르브-아모일]페닐]-2-메틸-5-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)피라졸 -3-카복사미드; 및 d) 2-클로로-N-(1-시아노시클로프로필)-5-[1-[2-메틸-5-(1,1,2,2,2-펜타플루오로에틸)-4-(트리플루오로메틸)피라졸-3- 일]피라졸-4-일]벤즈아미드;B3) a) 2-(3-에틸술포닐-2-피리딜)-3-메틸-6-(트리플루오로메틸피미다조[4,5-b]피리딘으로 이루어진 군으로부터 선택되는 피리딜술폰 및 b) 2-(3-틸설포닐-2-피리딜)-5-(트라이플루오로메틸설포닐)-1,3-벤족사졸; B4) 스피로피디온; B5) 아시노나피르; 및B6) 성분 1) 및 성분 2)가 1000:1 내지 1:1000의 중량비로 존재하는 벤즈피리목산을 포함하는 것을 특징으로 하는 살충 혼합물.