1,3-oxazoline and 1,3-thiazoline derivatives, method for producing the same and their use as pesticides1,3-oxazoline and 1,3-thiazoline derivatives having formula (I), wherein the symbols have the following meanings: A represents phenyl, pyridyl, pyrimidinyl, pyrazinyl, pyrazolyl or thienyl; E represents a single bond, (C1-C4)-alkylene, -O-CH2- or CH2-O-; G represents a radical of group (a), (b), (c) and (d) and Z represents oxygen or sulfur. Compounds of formula (I) exhibit very good acaricidal and insecticidal effect especially as regards spectrum of activity and effectiveness.1 of structural formula (i), 3-oxazoline derivative and 1,3-thiazoles quinoline derivant wherein various symbols have following implication:a is a phenyl, pyridyl, and pyrimidyl, pyrazinyl, pyrazolyl or thienyl, above-mentioned arbitrary group can be chosen wantonly by one or more radicals x and replace;x is identical or differenta) halogen, cyano group, nitro;b) (c 1-c 4) alkyl, (c 2-c 4) alkenyl, (c 2-c 4) alkynyl, (c 1-c 4) alkoxyl group, (c 1-c 4) alkylthio, (c 1-c 4) alkyl sulphinyl, (c 3-c 8) cycloalkyl, (c 4-c 8) cycloalkenyl, phenyl, the group of group b is optional to be selected from following one group group and to replace by one or more: halogen, cyano group, (c 1-c 4) alkyl, (c 1-c 4) haloalkyl, (c 1-c 4) alkoxyl group and (c 1-c 4) halogenated alkoxy; e is a singly-bound, (c 1-c 4) alkylidene group ,-o-ch 2-or-ch 2-o-; g is selected from following one group of group: z is oxygen or sulphur;r 1, r 2and r 3can be identical or different, represent hydrogen, halogen, (c 1-c 4) haloalkyl, (c 1-c 4) alkyl, (c 1-c 4) alkoxyl group, (c 1-c 4) halogenated alkoxy or cyano group; r 4be hydrogen or group (c 1-c 8) alkyl, (c 2-c 8) alkenyl, (c 2-c 8) alkynyl, (c 3-c 8) cycloalkyl, (c 3-c 8) cycloalkenyl, (c 4-c 10) cycloalkylalkyl or (c 7-c 12) phenylalkyl, above-mentioned arbitrary group can be chosen wantonly by one or more following substituting group and replace: halogen, (c 1-c 4) alkyl, (c 1-c 3) haloalkyl, (c 1-c 4) alkoxyl group, (c 1-c 3) halogenated alkoxy, (c 1-c 3) alkylthio, (c 3-c 8) cycloalkyl, (c 7-c 12) the phenyl alkoxyl group, (c 2-c 4) alkyl-carbonyl, alkoxy carbonyl, (c 2-c 6) alkyl-and (c 3-c 9) dialkyl amido-carbonyl, cyano group and three (c 1-c 4) the alkyl silyl; r 5and r 6can be identical or different, representative a) hydrogen, halogen, cyano group, formyl radical, (c 2-c 5) alkyl-carbonyl, (c 2-c 8) alkoxy carbonyl, (c 3-c 9) alkyl-and dialkyl amino carbonyl, b) (c 1-c 8) alkyl, (c 3-c 8) cycloalkyl, (c 4-c 8) cycloalkenyl, (c 1-c 8) alkoxyalkyl, (c 1-c 8) alkylthio, (c 1-c 8) alkyl sulphinyl, (c 1-c 8) alkyl sulphonyl, nr 7r 8, phenyl, phenoxy group, (c 7-c 12) phenylalkyl, (c 7-c 12) the phenyl alkoxyl group, heterocyclic radical, heterocyclic oxy group derivative, heterocycle (c 1-c 4) alkoxyl group, (c 3-c 12) heterocyclylalkyl, each group of group b is optional to be selected from following one group group and to replace by one or more: halogen, (c 1-c 4) alkyl, (c 1-c 3) haloalkyl, (c 1-c 3) alkoxyl group, (c 1-c 3) halogenated alkoxy, (c 1-c 3) alkylthio, nr 7r 8, alkyl-carbonyl (c 2-c 5), alkoxy carbonyl (c 2-c 8), an alkyl-and dialkyl amino carbonyl (c 3-c 9), cyano group and three (c 1-c 4) the alkyl silyl; c) (c 1-c 8) alkoxyl group, each group of group c is optional to be selected from following one group group and to replace by one or more: halogen, (c 1-c 3) alkylthio, nr 7r 8, alkyl-carbonyl (c 2-c 5), alkoxy carbonyl (c 2-c 8), an alkyl-and dialkyl amino carbonyl (c 3-c 9), cyano group and three (c 1-c 4) the alkyl silyl; d) r 5and r 6pass through b) described in two groups ring that is formed by connecting, preferred (c 3-c 5) alkylidene group, (c 2-c 4) alkylene oxide group, (c 1-c 3) alkylene dioxo base, (c 2-c 4) alkylidene amino or alkylene sulfenyl (c 2-c 4); r 7and r 8can be identical or different, representative a) hydrogen;b) optional by one or more following substituting groups: halogen, (c 1-c 4) alkyl, (c 1-c 3) haloalkyl, (c 1-c 4) alkoxyl group, (c 1-c 3) halogenated alkoxy, (c 1-c 3) alkylthio, (c 1-c 3) alkylamino, (c 1-c 3) dialkyl amido, (c 3-c 8) cycloalkyl, cyano group and three (c 1-c 4) (the c that replaces of alkyl silyl 1-c 8) alkyl, (c 3-c 8) cycloalkyl, (c 7-c 12) phenylalkyl, (c 1-c 6) alkyl-carbonyl, (c 1-c 6) alkyl sulphonyl; or c) r 7and r 8form alkylidene group (c together 3-c 7), (c 3-c 7) oxa--, azepine-or thia-alkylidene group, (c 3-c 7) alkylidene group carbonyl or (c 3-c 7) the alkylidene group alkylsulfonyl.
1,3-옥사졸린 및 1,3-티아졸린 유도체, 그의 제조방법 및살충제로서의 그의 용도본 발명은 하기 화학식 I의 1,3-옥사졸린 및 1,3-티아졸린 유도체에 관한 것이다.화학식 I상기 식에서,A는 페닐, 피리딜, 피리미딘일, 피라진일, 피라졸릴 또는 티에닐이고;E는 단일결합, (C1-C4)알킬렌, -O-CH2- 또는 -CH2-O-이고;G는 로 이루어지는 군으로부터 선택된 라디칼이고;Z는 산소 또는 황이다.화학식 I의 화합물은 특히 작용 및 효능에 있어서 매우 양호한 진드기 구충 및 살충 작용을 갖는다.하기 화학식 I의 1,3-옥사졸린 유도체 및 1,3-티아졸린 유도체. 화학식 I [이미지] 상기 식에서, A는 페닐, 피리딜, 피리미딘일, 피라진일, 피라졸릴 또는 티에닐이되, 이들 기의 각각은 1개 이상의 라디칼 X로 선택적으로 치환되고; X는 동일 또는 상이한 a) 할로겐, 시아노, 니트로; b) (C1-C4)알킬, (C2-C4)알케닐, (C2-C4)알키닐, (C1-C4)알콕시, (C1-C4)알킬티오, (C1-C4)알킬술피닐, (C3-C8)사이클로알킬, (C4-C8)사이클로알케닐, 페닐이되, b기의 라디칼은 할로겐, 시아노, (C1-C4)알킬, (C1-C4)할로알킬, (C1-C4)알콕시 및 (C1-C4)할로알콕시로 이루어지는 군으로부터 선택된 1개 이상의 라디칼로 선택적으로 치환되고; E는 단일결합, (C1-C4)알킬렌, -O-CH2- 또는 -CH2-O-이고;G는 [이미지] [이미지] 로 이루어지는 군으로부터 선택된 라디칼이고; Z는 산소 또는 황이고; R1, R2 및 R3은 동일 또는 상이한 수소, 할로겐, (C1-C4)할로알킬, (C1-C4)알킬, (C1-C4)알콕시, (C1-C4)할로알콕시 또는 시아노이고; R4는 수소이거나 또는 (C1-C8)알킬, (C2-C8)알케닐, (C2-C8)알키닐, (C3-C8)사이클로알킬, (C3-C8)사이클로알케닐, (C4-C10)사이클로알킬알킬 또는 (C7-C12)페닐알킬이되, 이들 기의 각각은 할로겐, (C1-C4)알킬, (C1-C3)할로알킬, (C1-C4)알콕시, (C1-C3)할로알콕시, (C1-C3)알킬티오, (C3-C8)사이클로알킬, (C7-C12)페닐알콕시, (C2-C4)알킬카보닐, 알콕시카보닐, (C2-C6)모노알킬- 및 (C3-C9)디알킬아미노카보닐, 시아노 및 트리(C1-C4)알킬실릴로 이루어지는 군으로부터 선택된 1개 이상의 치환기로 선택적으로 치환되고;R5 및 R6은 동일 또는 상이한 a) 수소, 할로겐, 시아노, 포르밀, (C2-C5)알킬카보닐, (C2-C8)알콕시카보닐, (C3-C9)모노알킬- 및 디알킬아미노카보닐, b) (C1-C8)알킬, (C3-C8)사이클로알킬, (C4-C8)사이클로알케닐, (C1-C8)알콕시알킬, (C1-C8)알킬티오, (C1-C8)알킬술피닐, (C1-C8)알킬설포닐, NR7R8, 페닐, 페녹시, (C7-C12)페닐알킬, (C7-C12)페닐알콕시, 헤테로사이클릴, 헤테로사이클릴옥시 유도체, 헤테로사이클릴(C1-C4)알콕시, (C3-C12)헤테로사이클릴알킬이되, b기의 각각은 할로겐, (C1-C4)알킬, (C1-C3)할로알킬, (C1-C3)알콕시, (C1-C3)할로알콕시, (C1-C3)알킬티오, NR7R8, 알킬카보닐(C2-C5), 알콕시카보닐(C2-C8), 모노알킬- 및 디알킬아미노카보닐(C3-C9), 시아노 및 트리(C1-C4)알킬실릴로 이루어지는 군으로부터 선택된 1개 이상의 라디칼로 선택적으로 치환되고; c) (C1-C8)알콕시이되, 이 c기의 각각은 할로겐, (C1-C3)알킬티오, NR7R8, 알킬카보닐(C2-C5), 알콕시카보닐(C2-C8), 모노알킬- 및 디알킬아미노카보닐(C3-C9), 시아노 및 트리(C1-C4)알킬실릴로 이루어지는 군으로부터 선택된 1개 이상의 라디칼로 선택적으로 치환되고;d) R5 및 R6은 b)에서 언급된 기중 2개를 연결시킴으로써 생기는 환을 함께 형성하되, 바람직하게는 (C3-C5)알킬렌, (C2-C4)알킬렌옥시, (C1-C3)알킬렌디옥시, (C2-C4)알킬렌아미노 또는 알킬렌티오(C2-C4)이고; R7 및 R8은 동일 또는 상이한 a) 수소; b) 할로겐, (C1-C4)알킬, (C1-C3)할로알킬, (C1-C4)알콕시, (C1-C3)할로알콕시, (C1-C3)알킬티오, (C1-C3)알킬아미노, (C1-C3)디알킬아미노, (C3-C8)사이클로알킬, 시아노 및 트리(C1-C4)알킬실릴로 이루어지는 군으로부터 선택된 1개 이상의 라디칼로 선택적으로 치환된 (C1-C8)알킬, (C3-C8)사이클로알킬, (C7-C12)페닐알킬, (C1-C6)알킬카보닐, (C1-C6)알킬설포닐이거나; 또는 c) R7 및 R8은 함께 알킬렌(C3-C7), (C3-C7)옥사-, 아자- 또는 티아알킬렌, (C3-C7)알킬렌카보닐 또는 (C3-C7)알킬렌설포닐이다.