3-arylquinazolin-4-one compounds for combating invertebrate pestsThe present invention relates to the 3-arylquinazolin-4-one compounds of the formula (I) and the salts thereof, formula (I) wherein n is O, 1 or 2; X is O, S or N-R4; Y1 is N or CH; Y2 is N or C-R5; R1 is C1-C10-alkyl, C1-C10-haloalkyl, C2-C10-alkenyl, C2-C10-haloalkenyl, C2-C10-alkynyl, C2-C10-haloalkynyl, C3-C12-cycloalkyl, C5-C12-cycloalkenyl, C3-C12-cycloalkyl-C1-C4-alkyl, C5-C12-cycloalkenyl-C1-C4-alkyl, where the cycloalkyl radical and the cycloalkenyl radical in the last four mentioned radicals are unsubstituted, partially or fully halogenated and/or carry 1, 2, 3, 4, or 5 C1-C4-alkyl radicals; R2 is hydrogen, halogen, CN, C(Z)NH2, C1-C4-alkyl or C1-C4-haloalkyl, wherein Z is O, S or NR6; and the variables k, R, R3, R4, R5 and R6 are as defined in the claims. The invention also relates to the use of novel compounds of formula (I) for combating invertebrate pests and to a method for controlling invertebrate pests. The invention also relates to a plant propagation material and to an agricultural composition comprising a 3-arylquinazolin-4-one compound of formula (I).But 1.3-aryl-quinazoline-4-ketone compound and agricultural salt thereof:WhereinK is 0,1,2,3 or 4;N is 0,1 or 2;X is O, S or N-R 4Y 1Be N or CH; Y 2Be N or C-R 5R is selected from halogen, CN, NO 2, C 1-C 4Alkyl, C 1-C 4Haloalkyl, C 2-C 4Alkenyl, C 1-C 4Halogenated alkenyl, C 2-C 4Alkynyl, C 1-C 4Halo alkynyl, C 1-C 4Alkoxy-C 1-C 4Alkyl, C 1-C 4Alkoxyl group, C 1-C 4Halogenated alkoxy, C 1-C 4Alkylthio, C 1-C 4Halogenated alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Haloalkyl sulfinyl, C 1-C 4Alkyl sulphonyl and C 1-C 4Halogenated alkyl sulfonyl is 2,3 or 4 for k, and R can be identical or different; R 1Be C 1-C 10Alkyl, C 1-C 10Haloalkyl, C 2-C 10Alkenyl, C 2-C 10Halogenated alkenyl, C 2-C 10Alkynyl, C 2-C 10Halo alkynyl, C 3-C 12Naphthenic base, C 5-C 12Cycloalkenyl group, C 3-C 12Naphthenic base-C 1-C 4Alkyl, C 5-C 12Cycloalkenyl group-C 1-C 4Alkyl, naphthenic base and the cycloalkenyl group in 4 groups mentioning after wherein be not substituted, partly or entirely by halo and/or have 1,2,3,4 or 5 C 1-C 4Alkyl; R 2Be hydrogen, halogen, CN, C (Z) NH 2, C 1-C 4Alkyl or C 1-C 4Haloalkyl, wherein Z is O, S or NR 6R 3Be hydrogen, OH, halogen, CN, C 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyl group, C 1-C 4Halogenated alkoxy, C 1-C 4Alkylthio, C 1-C 4Halogenated alkylthio, C 1-C 4Alkyl sulphinyl, C 1-C 4Haloalkyl sulfinyl, C 1-C 4Alkyl sulphonyl or C 1-C 4Halogenated alkyl sulfonyl; R 4Be selected from hydrogen, C 1-C 6Alkyl, C 1-C 6Haloalkyl, C 2-C 6Alkenyl, C 2-C 6Halogenated alkenyl, C 2-C 6Alkynyl, C 2-C 6Halo alkynyl, C 1-C 6Alkoxy-C 1-C 4Alkyl, C 1-C 6Alkoxyl group, C 1-C 6Halogenated alkoxy, C 2-C 6Alkenyloxy, C 2-C 6Halo alkenyloxy, C 2-C 6Alkynyloxy group, C 2-C 6Halo alkynyloxy group, C 3-C 6Naphthenic base, C 5-C 6Cycloalkenyl group, C 3-C 6Naphthenic base-C 1-C 4Alkyl, C 5-C 6Cycloalkenyl group-C 1-C 4Alkyl, C 3-C 6Cycloalkyloxy, C 5-C 6Cyclenes oxygen base, C 3-C 6Naphthenic base-C 1-C 4Alkoxyl group, C 5-C 6Cycloalkenyl group-C 1-C 4Alkoxyl group, naphthenic base and the cycloalkenyl group in 8 groups mentioning after wherein be not substituted, partly or entirely by halo and/or have 1,2,3,4 or 5 C 1-C 4Alkyl, Phenyl, phenyl-C 1-C 4Alkyl, phenoxy and phenyl-C 1-C 4Alkoxyl group, wherein phenyl, phenyl-C 1-C 4Alkyl, phenyl-C 1-C 4The benzyl ring of alkoxyl group and phenoxy is not substituted or is selected from halogen, C by 1,2,3,4 or 5 1-C 4Alkyl, C 1-C 4Haloalkyl, C 1-C 4Alkoxyl group and C 1-C 4The substituting group of halogenated alkoxy replaces; With R 5Be hydrogen, halogen, CN, C (Z) NH 2, C 1-C 4Alkyl or C 1-C 4Haloalkyl, wherein Z is O, S or NR 6R 6Have R 4One of the implication of giving.
무척추 해충을 퇴치하기 위한 3-아릴퀴나졸린-4-온 화합물본 발명은 화학식 (I)의 3-아릴퀴나졸린-4-온 화합물 및 그의 염에 관한 것이다. <화학식 I> 상기 식에서 n은 0, 1 또는 2이고; X는 O, S 또는 N-R4이고; Y1은 N 또는 CH이고; Y2는 N 또는 C-R5이고; R1은 C1-C10-알킬, C1-C10-할로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C2-C10-할로알키닐, C3-C12-시클로알킬, C5-C12-시클로알케닐, C3-C12-시클로알킬-C1-C4-알킬, C5-C12-시클로알케닐-C1-C4-알킬이고, 여기서 마지막 언급된 4개 라디칼의 시클로알킬 라디칼 및 시클로알케닐 라디칼은 비치환되거나, 부분적으로 또는 완전히 할로겐화되고/되거나 1, 2, 3, 4 또는 5개의 C1-C4-알킬 라디칼을 가지고; R2는 수소, 할로겐, CN, C(Z)NH2, C1-C4-알킬 또는 C1-C4-할로알킬이고, 여기서 Z는 O, S 또는 NR6이고; 변수 k, R, R3, R4, R5 및 R6은 특허청구범위에 규정된 바와 같다. 본 발명은 또한 무척추 해충을 퇴치하기 위한 화학식 (I)의 신규 화합물의 용도 및 무척추 해충을 방제하는 방법에 관한 것이다. 본 발명은 또한 화학식 (I)의 3-아릴퀴나졸린-4-온 화합물을 포함하는 식물 번식 물질 및 농업용 조성물에 관한 것이다.하기 화학식 I의 3-아릴퀴나졸린-4-온 화합물 및 농업적으로 허용되는 그의 염.<화학식 I>[이미지]상기 식에서,k는 0, 1, 2, 3 또는 4이고; n은 O, 1 또는 2이고;X는 O, S 또는 N-R4는고;Y1은 N 또는 CH이고;Y2은 N 또는 C-R5이고;R은 할로겐, CN, NO2, C1-C4-알킬, C1-C4-할로알킬, C2-C4-알케닐, C1-C4-할로알케닐, C2-C4-알키닐, C1-C4-할로알키닐, C1-C4-알콕시-C1-C4-알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알킬티오, C1-C4-할로알킬티오, C1-C4-알킬술피닐, C1-C4-할로알킬술피닐, C1-C4-알킬술포닐 및 C1-C4-할로알킬술포닐로 구성되는 군으로부터 선택되고, 여기서 k가 2, 3 또는 4인 경우 R이 동일하거나 상이할 수 있고;R1은 C1-C10-알킬, C1-C10-할로알킬, C2-C10-알케닐, C2-C10-할로알케닐, C2-C10-알키닐, C2-C10-할로알키닐, C3-C12-시클로알킬, C5-C12-시클로알케닐, C3-C12-시클로알킬-C1-C4-알킬, C5-C12-시클로알케닐-C1-C4-알킬이고, 여기서 마지막 언급된 4개 라디칼의 시클로알킬 라디칼 및 시클로알케닐 라디칼은 비치환되거나, 부분적으로 또는 완전히 할로겐화되고/되거나 1, 2, 3, 4, 또는 5개의 C1-C4-알킬 라디칼을 가지고;R2는 수소, 할로겐, CN, C(Z)NH2, C1-C4-알킬 또는 C1-C4-할로알킬이고, 여기서 Z는 O, S 또는 NR6이고;R3은 수소, OH, 할로겐, CN, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시, C1-C4-할로알콕시, C1-C4-알킬티오, C1-C4-할로알킬티오, C1-C4-알킬술피닐, C1-C4-할로알킬술피닐, C1-C4-알킬술포닐 또는 C1-C4-할로알킬술포닐이고;R4는 수소, C1-C6-알킬, C1-C6-할로알킬, C2-C6-알케닐, C2-C6-할로알케닐, C2-C6-알키닐, C2-C6-할로알키닐, C1-C6-알콕시-C1-C4-알킬, C1-C6-알콕시, C1-C6-할로알콕시, C2-C6-알케닐옥시, C2-C6-할로알케닐옥시, C2-C6-알키닐옥시, C2-C6-할로알키닐옥시, C3-C6-시클로알킬, C5-C6-시클로알케닐, C3-C6-시클로알킬-C1-C4-알킬, C5-C6-시클로알케닐-C1-C4-알킬, C3-C6-시클로알콕시, C5-C6-시클로알켄옥시, C3-C6-시클로알킬-C1-C4-알콕시, C5-C6-시클로알케닐-C1-C4-알콕시 (여기서 마지막 언급된 8개 라디칼의 시클로알킬 라디칼 및 시클로알케닐 라디칼은 비치환되거나, 부분적으로 또는 완전히 할로겐화되고/되거나 1, 2, 3, 4, 또는 5개의 C1-C4-알킬 라디칼을 가짐),페닐, 페닐-C1-C4-알킬, 페닐옥시 및 페닐-C1-C4-알콕시 (여기서 페닐, 페닐-C1-C4-알킬, 페닐-C1-C4-알콕시 및 페녹시의 페닐 고리는 비치환되거나 또는 할로겐, C1-C4-알킬, C1-C4-할로알킬, C1-C4-알콕시 및 C1-C4-할로알콕시로부터 선택되는 1, 2, 3, 4 또는 5개의 치환기에 의해 치환됨)로 구성되는 군으로부터 선택되고;R5는 수소, 할로겐, CN, C(Z)NH2, C1-C4-알킬 또는 C1-C4-할로알킬이고, 여기서 Z는 O, S 또는 NR6이고;R6은 R4에 대해 제공된 의미 중 하나이다.