Carboxylic acid amide derivative and their use as pesticidesCarboxylic acid amide derivatives having formula (I) are disclosed, as well as several processes for preparing the same and their use as fungicides. In formula (I), Ar stands for optionally substituted arylene or heteroarylene; E stands for an 1-alken-1,1-diyl grouping that contains a rest R in position 2, a 2-aza-1-alken-1,1-diyl grouping that contains a rest R in position 2, an optionally substituted imino grouping (''azamethylene'', N-R), a 3-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 3-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1, a 3-thia-1-propen-2,3-diyl grouping that contains a rest R in position 1, a 1-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 1-aza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 1,3-diaza-1-propen-2,3-diyl grouping that contains a rest R in position 1 and a rest R in position 3, a 1-aza-3-oxa-1-propen-2,3-diyl grouping that contains a rest R in position 1, or for a 1-aza-3-thia-1-propen-2,3-diyl grouping that contains a rest R in position 1; G stands for a simple bond, oxygen, sulphur or alkandiyl, alkendiyl, alkindiyl or one of the groupings represented in the formula: -Q-CQ-, -CQ-Q-, -CH2-Q-, -Q-CH2-, -CQ-Q-CH2-, -CH2-Q-CQ-, -Q-CQ-CH2-, -Q-CQ-Q-CH2-, -N=N-, -S(O)n-, -CH2-S(O)n-, -CQ-, -S(O)n-CH2-, -C(R)=N-O-, -C(R)=N-O-CH2-, -N(R)-, -CQ-N(R)-, -N(R)-CQ-, -Q-CQ-N(R)-, -N=C(R)-Q-CH2-, -CH2-O-N=C(R)-, etc.General formula (i) compound wherein ar represents the arylidene or the heteroarylidene of replacement arbitrarily, and e is illustrated in 2 and contains radicals r 11-alkene-1,1-two bases perhaps are illustrated in 2 and contain radicals r 22-azepine-1-alkene-1,1-two bases, the perhaps imino-that replaces arbitrarily of expression (' azepine ethylidene ', n-r 3), perhaps be illustrated in 1 and contain radicals r 1and contain radicals r at 3 33-azepine-1-propylene-2,3-two bases perhaps are illustrated in 1 and contain radicals r is arranged 13-azepine-1-propylene-2,3-two bases perhaps are illustrated in 1 and contain radicals r 13-thia-1-propylene-2,3-two bases perhaps are illustrated in 1 and contain radicals r 2and 3 radicals r is contained in the position 31-azepine-1-propylene-2,3-two bases perhaps are illustrated in 1 and contain base the r of group 1and contain radicals r at 3 31-azepine-1-propylene-2,3-two bases, perhaps the table be shown in 1 and contain radicals r 2and contain radicals r at 3 31,3-diaza-1-third alkene-2,3-two bases perhaps are illustrated in 1 and contain radicals r 21-azepine-3-oxa--1-propylene -2,3-two bases perhaps are illustrated in 1 and contain radicals r 21-azepine-3-thia-1-propylene- 2,3-two bases, whereinr 1expression hydrogen, halogen or cyano group, the perhaps any in each case alkane that replaces of expression base, alkoxyl group, alkylthio, alkylamino or dialkylamino,r 2expression hydrogen, amino, hydroxyl or cyano group, perhaps expression replaces arbitrarily in each case alkyl, alkoxyl group, alkylamino or dialkylamino, andr 3expression hydrogen, cyano group or hydroxyl, the perhaps any in each case alkane that replaces of expression base, alkoxyl group, alkoxyalkyl, alkenyl, alkynyl group, cycloalkyl or cycloalkylalkyl, g are represented singly-bound, oxygen or a sulphur, and perhaps expression is in each case at random by the alkane 2 basis of halogen, hydroxyl, alkyl, haloalkyl or cycloalkyl substituted, olefin 2 base, alkyne two bases or following groups-q 1-cq 1-,-cq 1-q 1-,-ch 2-q 1-;-q 1-ch 2-,-cq 1-q 1-ch 2-,-ch 2-q 1-cq 1-,-q 1-cq 1-ch 2-,-q 1-cq 1-q 1-ch 2-,-n=n-,-s (o) n-,-ch 2-s (o) n-,-cq 1-,-s (o) n-ch 2-,-c (r 4)=n-o-,-c (r 4)=n-o-ch 2-,-n (r 5)-,-cq 1-n (r 5)-,-n (r 5)-cq 1-,-q 1-cq 1-n (r 5)-,-n=c (r 4)-q 1-ch 2-,-ch 2-o-n=c (r 4)-,-n (r 5)-cq 1-q 1,-cq 1-n (r 5)-cq 1-q 1,-n (r 5)-cq 1-q 1-ch 2-,-q 1-c (r 4)=n-o-ch 2-,-n (r 5)-c (r 4)=n-o-ch 2-,-o-ch 2-c-r 4)=n-o-ch 2-,-n=n-c (r 4)=n-o-ch 2-,-c (ch 3)-o-n=c (r 4)-,-c (=n-o-l)-c (r 4)=n-o-ch 2-,-c (=n-o-l)-c (r 4)-o-n=ch-,-c (=n-o-l)-c (r 4)-o-n=c (ch 3)-,-t-ar 1-or-t-ar 1-q 1-, whereinar 1arylidene, heteroarylidene, ring alkylidene group or heterocycle alkylidene group that expression replaces arbitrarily (be wherein one or more carbon atoms by heteroatoms, be non-carbon atom metathetical divalencethe aliphatic series ring),n represents 0,1 or 2,q 1expression oxygen or sulphur, r 4expression hydrogen, cyano group, perhaps any in each case alkyl, the alcoxyl that replaces of expression base, alkylthio, alkylamino, dialkylamino or cycloalkyl,r 5expression hydrogen, hydroxyl, cyano group, perhaps the alkyl that replaces arbitrarily in each case of expression, alkoxyl group or cycloalkyl,l represents hydrogen or alkyl, andt represent a singly-bound, oxygen, sulphur ,-ch 2-o-,-ch 2-s-or expression are got arbitrarily the alkane 2 basis in generation, q are represented oxygen or sulphur, and r represents hydrogen, amino, the perhaps alkyl, alkoxyl group, alkylamino or the dialkylamino that replace arbitrarily in each case of expression, y represent-co-,-cs-or-so 2-, and z represents in each case alkyl, alkenyl, alkynyl group, cycloalkyl, aryl or the heterocyclic radical of replacement arbitrarily.
카복실산 아미드 유도체 및 농약으로서의 그의 용도 본 발명은 신규한 카복스아미드 유도체, 다수의 그의 제조방법 및 살진균제로서의 그의 용도에 관한 것이다.일반식 (Ⅰ)의 화합물: [이미지] 상기 시에서, Ar은 임의로 치환된 아릴렌 또는 헤테로아릴렌을 나타내며, E는 2-위치에 래디칼 R1을 갖는 1-알켄-1,1-디일 그룹을 나타내거나, 2-위치에 래디칼 R2를 갖는 2-아자-1-알켄-1,1-디일 그룹을 나타내거나, 임의로 치환된 아미노 그룹(아자메틸렌, N-R3)을 나타내거나, 1-위치에 래디칼 R1 및 3-위치에 래디칼 R3를 갖는 3-아자-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R1을 갖는 3-아자-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R1을 갖는 3-티아-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R2 및 3-위치에 래디칼 R3를 갖는 1-아자-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R1 및 3-위치에 래디칼 R3를 갖는 1-아자-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R2 및 3-위치에 래디칼 R3를 갖는 1,3-디아자-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R2를 갖는 1-아자-3-옥사-1-프로펜-2,3-디일 그룹을 나타내거나, 1-위치에 래디칼 R2를 갖는 1-아자-3-티아-1-프로펜-2,3-디일 그룹을 나타내고, 여기에서, R1은 수소, 할로겐, 시아노, 또는 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬아미노 또는 디알킬아미노를 나타내며, R2는 수소, 아미노, 하이드록실, 시아노, 또는 각 경우에 임의로 치환된 알킬, 알콕시, 알킬아미노 또는 디알킬아미노를 나타내고, R3은 수소, 시아노, 하이드록실, 또는 각 경우에 임의로 치환된 알킬, 알콕시, 알콕시알킬, 알케닐, 알키닐, 사이클로알킬 또는 사이클로알킬알킬을 나타내며, G는 단일 결합, 산소, 황, 또는 각 경우에 임의로 할로겐-, 하이드록실-, 알킬-, 할로게노알킬- 또는 사이클로알킬-치환된 알칸디일, 알켄디일 또는 알킨디일을 나타내거나, 그룹 -Q1-CQ1-, -CQ1-Q1-, -CH2-Q1-, -Q1-CH2-, -CQ1-Q1-CH2-, -CH2-Q1-CQ1-, -Q1-CQ1-CH2-, -Q1-CQ1-Q1-CH2-, -N=N-, S(O)n-, -CH2-S(O)n-, -CQ1-, -S(O)n-CH2-, -C(R4)=N-O-, -C(R4)=N-O-CH 2-, -N(R5)-, -CQ1-N(R5)-, -N(R5)-CQ1-, -Q1-CQ1-N(R5)-, -N=C(R4)-Q 1-CH2-, -CH2-O-N=C(R4)-, -N-(R5)-CQ1-Q1-, -CQ1-N(R5)-CQ1-Q1-, -N-(R 5)-CQ1-Q1-CH2-, -Q1-C(R4)=N-O-CH2-, -N(R5)-C(R4)=N-O-CH2-, -O-CH2-C(R4)=N-O-CH2-, -N=N-C(R4)=N-O-CH2-, -C(CH3)-O-N=C(R4)-, -C(=N-O-L)-C(R4)=N-O-CH2-, -C(=N-O-L)-C(R 4)-O-N=CH-, -C(=N-O-L)-C(R4)-O-N=C(CH3)-, -T-Ar1- 및 -T-Ar1-Q 1- 중의 하나를 나타내며, 여기에서, Ar1은 임의로 치환된 아릴렌, 헤테로아릴렌, 사이클로알킬렌 또는 헤테로사이클로알킬렌(즉, 하나 또는 그 이상의 탄소 원자가 헤테로 원자, 즉 탄소이외의 원자에 의해 대체된 2가 지방족 환)을 나타내고, n은 0, 1 또는 2의 수를 나타내며, Q1은 산소 또는 황을 나타내고, R4는 수소, 시아노, 또는 각 경우에 임의로 치환된 알킬, 알콕시, 알킬티오, 알킬아미노, 디알킬아미노 또는 사이클로알킬을 나타내며, R5는 수소, 하이드록실, 시아노, 또는 각 경우에 임의로 치환된 알킬, 알콕시 또는 사이클로알킬을 나타내고, L은 수소 또는 알킬을 나타내며, T는 단일 결합, 산소, 황, -CH2-O-, -CH2-S- 또는 임의로 치환된 알칸디일을 나타내고, Q는 산소 또는 황을 나타내며, R은 수소, 아미노, 또는 각 경우에 임의로 치환된 알킬, 알콕시, 알킬아미노 또는 디알킬아미노를 나타내고, Y는 -CO-, -CS- 또는 -SO2-를 나타내며, Z는 각 경우에 임의로 치환된 알킬, 알케닐, 알키닐, 사이클로알킬, 아릴 또는 헤테로사이클릴을 나타낸다.