Along with UO2, what is the commonest form of uranium oxide?
doc-16700
The most common forms of uranium oxide are triuranium octoxide (U
3O
8) and UO
2. Both oxide forms are solids that have low solubility in water and are relatively stable over a wide range of environmental conditions. Triuranium octoxide is (depending on conditions) the most stable compound of uranium and is the form most commonly found in nature. Uranium dioxide is the form in which uranium is most commonly used as a nuclear reactor fuel. At ambient temperatures, UO
2 will gradually convert to U
3O
8. Because of their stability, uranium oxides are generally considered the preferred chemical form for storage or disposal.
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doc-16711
Salts of many oxidation states of uranium are water-soluble and may be studied in aqueous solutions. The most common ionic forms are U3+ (brown-red), U4+ (green), UO+
2 (unstable), and UO2+
2 (yellow), for U(III), U(IV), U(V), and U(VI), respectively. A few solid and semi-metallic compounds such as UO and US exist for the formal oxidation state uranium(II), but no simple ions are known to exist in solution for that state. Ions of U3+ liberate hydrogen from water and are therefore considered to be highly unstable. The UO2+
2 ion represents the uranium(VI) state and is known to form compounds such as uranyl carbonate, uranyl chloride and uranyl sulfate. UO2+
2 also forms complexes with various organic chelating agents, the most commonly encountered of which is uranyl acetate.
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doc-16716
Normal functioning of the kidney, brain, liver, heart, and other systems can be affected by uranium exposure, because, besides being weakly radioactive, uranium is a toxic metal. Uranium is also a reproductive toxicant. Radiological effects are generally local because alpha radiation, the primary form of 238U decay, has a very short range, and will not penetrate skin. Uranyl (UO2+
2) ions, such as from uranium trioxide or uranyl nitrate and other hexavalent uranium compounds, have been shown to cause birth defects and immune system damage in laboratory animals. While the CDC has published one study that no human cancer has been seen as a result of exposure to natural or depleted uranium, exposure to uranium and its decay products, especially radon, are widely known and significant health threats. Exposure to strontium-90, iodine-131, and other fission products is unrelated to uranium exposure, but may result from medical procedures or exposure to spent reactor fuel or fallout from nuclear weapons. Although accidental inhalation exposure to a high concentration of uranium hexafluoride has resulted in human fatalities, those deaths were associated with the generation of highly toxic hydrofluoric acid and uranyl fluoride rather than with uranium itself. Finely divided uranium metal presents a fire hazard because uranium is pyrophoric; small grains will ignite spontaneously in air at room temperature.
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doc-16714
Uranium carbides and uranium nitrides are both relatively inert semimetallic compounds that are minimally soluble in acids, react with water, and can ignite in air to form U
3O
8. Carbides of uranium include uranium monocarbide (UC), uranium dicarbide (UC
2), and diuranium tricarbide (U
2C
3). Both UC and UC
2 are formed by adding carbon to molten uranium or by exposing the metal to carbon monoxide at high temperatures. Stable below 1800 °C, U
2C
3 is prepared by subjecting a heated mixture of UC and UC
2 to mechanical stress. Uranium nitrides obtained by direct exposure of the metal to nitrogen include uranium mononitride (UN), uranium dinitride (UN
2), and diuranium trinitride (U
2N
3).
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doc-7817
Imperial College Boat Club
The Imperial College Boat Club was founded on 12 December 1919. The Gold medal winning GB 8+ at the 2000 Sydney Olympics had been based at Imperial College's recently refurbished boathouse and included 3 alumni of the college along with their coach Martin McElroy. The club has been highly successful, with many wins at Henley Royal Regatta including most recently in 2013 with victory in The Prince Albert Challenge Cup event. The club has been home to numerous National Squad oarsmen and women and is open to all rowers not just students of Imperial College London.
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doc-16717
The gas centrifuge process, where gaseous uranium hexafluoride (UF
6) is separated by the difference in molecular weight between 235UF6 and 238UF6 using high-speed centrifuges, is the cheapest and leading enrichment process. The gaseous diffusion process had been the leading method for enrichment and was used in the Manhattan Project. In this process, uranium hexafluoride is repeatedly diffused through a silver-zinc membrane, and the different isotopes of uranium are separated by diffusion rate (since uranium 238 is heavier it diffuses slightly slower than uranium-235). The molecular laser isotope separation method employs a laser beam of precise energy to sever the bond between uranium-235 and fluorine. This leaves uranium-238 bonded to fluorine and allows uranium-235 metal to precipitate from the solution. An alternative laser method of enrichment is known as atomic vapor laser isotope separation (AVLIS) and employs visible tunable lasers such as dye lasers. Another method used is liquid thermal diffusion.
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doc-7679
Consequently, steam reforming typically employs an excess of H
2O. Additional hydrogen can be recovered from the steam by use of carbon monoxide through the water gas shift reaction, especially with an iron oxide catalyst. This reaction is also a common industrial source of carbon dioxide:
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doc-7674
A molecular form called protonated molecular hydrogen (H+
3) is found in the interstellar medium, where it is generated by ionization of molecular hydrogen from cosmic rays. This charged ion has also been observed in the upper atmosphere of the planet Jupiter. The ion is relatively stable in the environment of outer space due to the low temperature and density. H+
3 is one of the most abundant ions in the Universe, and it plays a notable role in the chemistry of the interstellar medium. Neutral triatomic hydrogen H3 can only exist in an excited form and is unstable. By contrast, the positive hydrogen molecular ion (H+
2) is a rare molecule in the universe.
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doc-17340
The chemistry of zinc is dominated by the +2 oxidation state. When compounds in this oxidation state are formed the outer shell s electrons are lost, which yields a bare zinc ion with the electronic configuration [Ar]3d10. In aqueous solution an octahedral complex, [Zn(H
2O)6]2+ is the predominant species. The volatilization of zinc in combination with zinc chloride at temperatures above 285 °C indicates the formation of Zn
2Cl
2, a zinc compound with a +1 oxidation state. No compounds of zinc in oxidation states other than +1 or +2 are known. Calculations indicate that a zinc compound with the oxidation state of +4 is unlikely to exist.
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doc-7660
To avoid the implication of the naked "solvated proton" in solution, acidic aqueous solutions are sometimes considered to contain a less unlikely fictitious species, termed the "hydronium ion" (H
3O+). However, even in this case, such solvated hydrogen cations are more realistically conceived as being organized into clusters that form species closer to H
9O+
4. Other oxonium ions are found when water is in acidic solution with other solvents.
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doc-7823
Imperial College TV
ICTV (formerly STOIC (Student Television of Imperial College)) is Imperial College Union's TV station, founded in 1969 and operated from a small TV studio in the Electrical Engineering block. The department had bought an early AMPEX Type A 1-inch videotape recorder and this was used to produce an occasional short news programme which was then played to students by simply moving the VTR and a monitor into a common room. A cable link to the Southside halls of residence was laid in a tunnel under Exhibition Road in 1972. Besides the news, early productions included a film of the Queen opening what was then called College Block and interview programmes with DJ Mike Raven, Richard O'Brian and Monty Python producer Ian MacNaughton. The society was renamed to ICTV for the start of the 2014/15 academic year.
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