Where can oxonium ions be found?
doc-7660
To avoid the implication of the naked "solvated proton" in solution, acidic aqueous solutions are sometimes considered to contain a less unlikely fictitious species, termed the "hydronium ion" (H
3O+). However, even in this case, such solvated hydrogen cations are more realistically conceived as being organized into clusters that form species closer to H
9O+
4. Other oxonium ions are found when water is in acidic solution with other solvents.
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doc-7674
A molecular form called protonated molecular hydrogen (H+
3) is found in the interstellar medium, where it is generated by ionization of molecular hydrogen from cosmic rays. This charged ion has also been observed in the upper atmosphere of the planet Jupiter. The ion is relatively stable in the environment of outer space due to the low temperature and density. H+
3 is one of the most abundant ions in the Universe, and it plays a notable role in the chemistry of the interstellar medium. Neutral triatomic hydrogen H3 can only exist in an excited form and is unstable. By contrast, the positive hydrogen molecular ion (H+
2) is a rare molecule in the universe.
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doc-16711
Salts of many oxidation states of uranium are water-soluble and may be studied in aqueous solutions. The most common ionic forms are U3+ (brown-red), U4+ (green), UO+
2 (unstable), and UO2+
2 (yellow), for U(III), U(IV), U(V), and U(VI), respectively. A few solid and semi-metallic compounds such as UO and US exist for the formal oxidation state uranium(II), but no simple ions are known to exist in solution for that state. Ions of U3+ liberate hydrogen from water and are therefore considered to be highly unstable. The UO2+
2 ion represents the uranium(VI) state and is known to form compounds such as uranyl carbonate, uranyl chloride and uranyl sulfate. UO2+
2 also forms complexes with various organic chelating agents, the most commonly encountered of which is uranyl acetate.
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doc-16716
Normal functioning of the kidney, brain, liver, heart, and other systems can be affected by uranium exposure, because, besides being weakly radioactive, uranium is a toxic metal. Uranium is also a reproductive toxicant. Radiological effects are generally local because alpha radiation, the primary form of 238U decay, has a very short range, and will not penetrate skin. Uranyl (UO2+
2) ions, such as from uranium trioxide or uranyl nitrate and other hexavalent uranium compounds, have been shown to cause birth defects and immune system damage in laboratory animals. While the CDC has published one study that no human cancer has been seen as a result of exposure to natural or depleted uranium, exposure to uranium and its decay products, especially radon, are widely known and significant health threats. Exposure to strontium-90, iodine-131, and other fission products is unrelated to uranium exposure, but may result from medical procedures or exposure to spent reactor fuel or fallout from nuclear weapons. Although accidental inhalation exposure to a high concentration of uranium hexafluoride has resulted in human fatalities, those deaths were associated with the generation of highly toxic hydrofluoric acid and uranyl fluoride rather than with uranium itself. Finely divided uranium metal presents a fire hazard because uranium is pyrophoric; small grains will ignite spontaneously in air at room temperature.
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doc-7683
In its turn, under anaerobic conditions, the ferrous hydroxide (Fe(OH)
2 ) can be oxidized by the protons of water to form magnetite and molecular hydrogen. This process is described by the Schikorr reaction:
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doc-7679
Consequently, steam reforming typically employs an excess of H
2O. Additional hydrogen can be recovered from the steam by use of carbon monoxide through the water gas shift reaction, especially with an iron oxide catalyst. This reaction is also a common industrial source of carbon dioxide:
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doc-7682
Under anaerobic conditions, iron and steel alloys are slowly oxidized by the protons of water concomitantly reduced in molecular hydrogen (H
2). The anaerobic corrosion of iron leads first to the formation of ferrous hydroxide (green rust) and can be described by the following reaction:
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doc-17355
Zinc chloride is often added to lumber as a fire retardant and can be used as a wood preservative. It is also used to make other chemicals. Zinc methyl (Zn(CH3)
2) is used in a number of organic syntheses. Zinc sulfide (ZnS) is used in luminescent pigments such as on the hands of clocks, X-ray and television screens, and luminous paints. Crystals of ZnS are used in lasers that operate in the mid-infrared part of the spectrum. Zinc sulfate is a chemical in dyes and pigments. Zinc pyrithione is used in antifouling paints.
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doc-9193
In the US, one kilowatt-hour (3.6 MJ) of electricity currently causes an average 1.34 pounds (610 g) of CO
2 emission. Assuming the average light bulb is on for 10 hours a day, a 40-watt bulb will cause 196 pounds (89 kg) of CO
2 emission per year. The 6-watt LED equivalent will only cause 30 pounds (14 kg) of CO
2 over the same time span. A building’s carbon footprint from lighting can therefore be reduced by 85% by exchanging all incandescent bulbs for new LEDs if a building previously used only incandescent bulbs.
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doc-7678
This reaction is favored at low pressures but is nonetheless conducted at high pressures (2.0  MPa, 20 atm or 600 inHg). This is because high-pressure H
2 is the most marketable product and Pressure Swing Adsorption (PSA) purification systems work better at higher pressures. The product mixture is known as "synthesis gas" because it is often used directly for the production of methanol and related compounds. Hydrocarbons other than methane can be used to produce synthesis gas with varying product ratios. One of the many complications to this highly optimized technology is the formation of coke or carbon:
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doc-8701
La carriera musicale di West è stata definita da frequenti cambiamenti stilistici e lo ha visto sviluppare ed esplorare una varietà di diversi approcci e generi musicali nel corso del suo lavoro. Alla domanda sulle sue ispirazioni musicali, ha chiamato A Tribe Called Quest, Stevie Wonder, Michael Jackson, George Michael, LL Cool J, Phil Collins e Madonna come primi interessi. Ha inoltre descritto il musicista David Bowie come una delle sue "più importanti ispirazioni" e ha definito il produttore Puff Daddy "la più importante figura culturale della mia vita". All' inizio della sua carriera, West è stato pioniere di uno stile di produzione soprannominato "chipmunk soul" che utilizzava campioni vocali pitched-up, di solito da soul e R&B canzoni, insieme con la sua batteria e strumentazione. La sua prima importante release con il suo stile di campionamento vocale soulful è stato "This Can' t Be Life", un brano tratto da The Dynasty di Jay-Z: Roc La Familia. West ha detto che il produttore di Wu-Tang Clan RZA lo ha influenzato nel suo stile, e ha chiamato rapper Wu-Tang Ghostface Killah e Ol' Dirty Bastard come ispirazioni. RZA ha parlato positivamente dei confronti, affermando in un' intervista per Rolling Stone:"Tutto buono. Ho ottenuto super rispetto per Kanye[][][le] sta per ispirare la gente ad essere come lui".
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