How is hydrogen produced when there is no atmospheric oxygen?
doc-7684
In the absence of atmospheric oxygen (O
2), in deep geological conditions prevailing far away from Earth atmosphere, hydrogen (H
2) is produced during the process of serpentinization by the anaerobic oxidation by the water protons (H+) of the ferrous (Fe2+) silicate present in the crystal lattice of the fayalite (Fe
2SiO
4, the olivine iron-endmember). The corresponding reaction leading to the formation of magnetite (Fe
3O
4), quartz (SiO
2) and hydrogen (H
2) is the following:
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doc-7655
Compounds of hydrogen are often called hydrides, a term that is used fairly loosely. The term "hydride" suggests that the H atom has acquired a negative or anionic character, denoted H−, and is used when hydrogen forms a compound with a more electropositive element. The existence of the hydride anion, suggested by Gilbert N. Lewis in 1916 for group I and II salt-like hydrides, was demonstrated by Moers in 1920 by the electrolysis of molten lithium hydride (LiH), producing a stoichiometry quantity of hydrogen at the anode. For hydrides other than group I and II metals, the term is quite misleading, considering the low electronegativity of hydrogen. An exception in group II hydrides is BeH
2, which is polymeric. In lithium aluminium hydride, the AlH−
4 anion carries hydridic centers firmly attached to the Al(III).
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doc-7674
A molecular form called protonated molecular hydrogen (H+
3) is found in the interstellar medium, where it is generated by ionization of molecular hydrogen from cosmic rays. This charged ion has also been observed in the upper atmosphere of the planet Jupiter. The ion is relatively stable in the environment of outer space due to the low temperature and density. H+
3 is one of the most abundant ions in the Universe, and it plays a notable role in the chemistry of the interstellar medium. Neutral triatomic hydrogen H3 can only exist in an excited form and is unstable. By contrast, the positive hydrogen molecular ion (H+
2) is a rare molecule in the universe.
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doc-17340
The chemistry of zinc is dominated by the +2 oxidation state. When compounds in this oxidation state are formed the outer shell s electrons are lost, which yields a bare zinc ion with the electronic configuration [Ar]3d10. In aqueous solution an octahedral complex, [Zn(H
2O)6]2+ is the predominant species. The volatilization of zinc in combination with zinc chloride at temperatures above 285 °C indicates the formation of Zn
2Cl
2, a zinc compound with a +1 oxidation state. No compounds of zinc in oxidation states other than +1 or +2 are known. Calculations indicate that a zinc compound with the oxidation state of +4 is unlikely to exist.
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doc-7660
To avoid the implication of the naked "solvated proton" in solution, acidic aqueous solutions are sometimes considered to contain a less unlikely fictitious species, termed the "hydronium ion" (H
3O+). However, even in this case, such solvated hydrogen cations are more realistically conceived as being organized into clusters that form species closer to H
9O+
4. Other oxonium ions are found when water is in acidic solution with other solvents.
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doc-17348
Zinc metal is produced using extractive metallurgy. After grinding the ore, froth flotation, which selectively separates minerals from gangue by taking advantage of differences in their hydrophobicity, is used to get an ore concentrate. This concentrate consists of about 50% zinc with the rest being sulfur (32%), iron (13%), and SiO
2 (5%). The composition of this is normally zinc sulfide (80% to 85%), iron sulfide (7.0% to 12%), lead sulfide (3.0% to 5.0%) silica (2.5% to 3.5%), and cadmium sulfide (0.35% to 0.41%).
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doc-7688
Apart from its use as a reactant, H
2 has wide applications in physics and engineering. It is used as a shielding gas in welding methods such as atomic hydrogen welding. H2 is used as the rotor coolant in electrical generators at power stations, because it has the highest thermal conductivity of any gas. Liquid H2 is used in cryogenic research, including superconductivity studies. Because H
2 is lighter than air, having a little more than 1⁄14 of the density of air, it was once widely used as a lifting gas in balloons and airships.
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doc-7686
Large quantities of H
2 are needed in the petroleum and chemical industries. The largest application of H
2 is for the processing ("upgrading") of fossil fuels, and in the production of ammonia. The key consumers of H
2 in the petrochemical plant include hydrodealkylation, hydrodesulfurization, and hydrocracking. H
2 has several other important uses. H
2 is used as a hydrogenating agent, particularly in increasing the level of saturation of unsaturated fats and oils (found in items such as margarine), and in the production of methanol. It is similarly the source of hydrogen in the manufacture of hydrochloric acid. H
2 is also used as a reducing agent of metallic ores.
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doc-16711
Salts of many oxidation states of uranium are water-soluble and may be studied in aqueous solutions. The most common ionic forms are U3+ (brown-red), U4+ (green), UO+
2 (unstable), and UO2+
2 (yellow), for U(III), U(IV), U(V), and U(VI), respectively. A few solid and semi-metallic compounds such as UO and US exist for the formal oxidation state uranium(II), but no simple ions are known to exist in solution for that state. Ions of U3+ liberate hydrogen from water and are therefore considered to be highly unstable. The UO2+
2 ion represents the uranium(VI) state and is known to form compounds such as uranyl carbonate, uranyl chloride and uranyl sulfate. UO2+
2 also forms complexes with various organic chelating agents, the most commonly encountered of which is uranyl acetate.
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doc-14711
^1 Also considered part of Rusyns
^2 Considered transitional between Ukrainians and Belarusians
^3 The ethnic affiliation of the Lemkos has become an ideological conflict. It has been alleged that among the Lemkos the idea of "Carpatho-Ruthenian" nation is supported only by Lemkos residing in Transcarpathia and abroad
^4 Most inhabitants of historic Moravia considered themselves as Czechs but significant amount declared their Moravian nationality, different from that Czech (although people from Bohemia and Moravia use the same official language).
^5 Also considered Poles.
^6 There are sources that show Silesians as part of the Poles. Parts of the southmost population of Upper Silesia is sometimes considered Czech (controversial).
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doc-7675
H
2 is produced in chemistry and biology laboratories, often as a by-product of other reactions; in industry for the hydrogenation of unsaturated substrates; and in nature as a means of expelling reducing equivalents in biochemical reactions.
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