csv = StringIO("""index,A,B
0,1,0.0
1,1,3.0
2,1,6.0
3,2,0.0
4,2,5.0
5,2,7.0""")
df = pandas.read_csv(csv, index_col='index')
groups = df.groupby(by=['A'])
print(groups.apply(lambda g: g[g['B'] == g['B'].max()]))
Python pandas – фильтровать строки после groupby