Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core
Toshiki Yamaguchi, Shigeyuki Masaoka, Ken Sakai
Inorganic and Analytical Chemistry
An air-stable dinuclear iron-dithiolene complex with an Fe 2(μ-S) 2 core, [Fe III(mnt) 2] 2 2- (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH 3CO 2H, has been found to serve as a major proton mediator during the electrocatalytie hydrogen evolution.
https://doi.org/10.1246/cl.2009.434
10.1246/cl.2009.434
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Water Type Chemistry 100%
Air Material Science 100%
Iron Material Science 100%
Iron Complex Material Science 100%
Acid Chemistry 50%
Reduction Chemistry 50%
Hydrogen Chemistry 50%
Proton Chemistry 50%
Yamaguchi, T., Masaoka, S., & Sakai, K. (2009). Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core. Chemistry Letters, 38(5), 434-435. https://doi.org/10.1246/cl.2009.434
Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core. / Yamaguchi, Toshiki; Masaoka, Shigeyuki; Sakai, Ken.
In: Chemistry Letters, Vol. 38, No. 5, 2009, p. 434-435.
Yamaguchi, T, Masaoka, S & Sakai, K 2009, 'Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core', Chemistry Letters, vol. 38, no. 5, pp. 434-435. https://doi.org/10.1246/cl.2009.434
Yamaguchi T, Masaoka S, Sakai K. Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core. Chemistry Letters. 2009;38(5):434-435. doi: 10.1246/cl.2009.434
Yamaguchi, Toshiki ; Masaoka, Shigeyuki ; Sakai, Ken. / Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core. In: Chemistry Letters. 2009 ; Vol. 38, No. 5. pp. 434-435.
@article{6122a1d311a043c2b0d222efe8c9abbe,
title = "Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core",
abstract = "An air-stable dinuclear iron-dithiolene complex with an Fe 2(μ-S) 2 core, [Fe III(mnt) 2] 2 2- (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH 3CO 2H, has been found to serve as a major proton mediator during the electrocatalytie hydrogen evolution.",
author = "Toshiki Yamaguchi and Shigeyuki Masaoka and Ken Sakai",
doi = "10.1246/cl.2009.434",
journal = "Chemistry Letters",
publisher = "The Chemical Society of Japan",
T1 - Hydrogen production from water catalyzed by an air-stable di-iron complex with a bio-relevant Fe 2(μ-S) 2 core
AU - Yamaguchi, Toshiki
AU - Masaoka, Shigeyuki
AU - Sakai, Ken
N2 - An air-stable dinuclear iron-dithiolene complex with an Fe 2(μ-S) 2 core, [Fe III(mnt) 2] 2 2- (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH 3CO 2H, has been found to serve as a major proton mediator during the electrocatalytie hydrogen evolution.
AB - An air-stable dinuclear iron-dithiolene complex with an Fe 2(μ-S) 2 core, [Fe III(mnt) 2] 2 2- (mnt = maleonitriledithiolate), has been found to serve as an electrode catalyst toward the reduction of water into molecular hydrogen with an overpotential of 560 mV. The acid form of a buffer reagent, such as CH 3CO 2H, has been found to serve as a major proton mediator during the electrocatalytie hydrogen evolution.
U2 - 10.1246/cl.2009.434
DO - 10.1246/cl.2009.434
JO - Chemistry Letters
JF - Chemistry Letters