Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os)
Deven P. Estes, Aaron K. Vannucci, Ariel R. Hall, Dennis L. Lichtenberger, Jack R. Norton
Several different pKa values for the complex (η5-C5H5)Fe(CO)2H (FpH) in acetonitrile are present in the literature, ranging over 7 orders of magnitude. As a result, the energy of its Fe-H bond is also in dispute, making it difficult to predict the reactivity of this complex. The pKa, bond dissociation enthalpy, bond dissociation free energy, and hydricity of FpH have been measured. The pKa values of analogous group 8 hydrides have been determined, and the energies of the M-H bonds and the hydricity of FpH have been established.
https://doi.org/10.1021/om2001519
10.1021/om2001519
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Hydrogen bonds Chemical Compounds
hydrogen bonds Physics & Astronomy
Carbon Monoxide Chemical Compounds
Thermodynamics Chemical Compounds
dissociation Physics & Astronomy
thermodynamics Physics & Astronomy
acetonitrile Physics & Astronomy
Estes, D. P., Vannucci, A. K., Hall, A. R., Lichtenberger, D. L., & Norton, J. R. (2011). Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os). Organometallics, 30(12), 3444-3447. https://doi.org/10.1021/om2001519
Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os). / Estes, Deven P.; Vannucci, Aaron K.; Hall, Ariel R.; Lichtenberger, Dennis L.; Norton, Jack R.
In: Organometallics, Vol. 30, No. 12, 27.06.2011, p. 3444-3447.
Estes, DP, Vannucci, AK, Hall, AR, Lichtenberger, DL & Norton, JR 2011, 'Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os)', Organometallics, vol. 30, no. 12, pp. 3444-3447. https://doi.org/10.1021/om2001519
Estes DP, Vannucci AK, Hall AR, Lichtenberger DL, Norton JR. Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os). Organometallics. 2011 Jun 27;30(12):3444-3447. https://doi.org/10.1021/om2001519
Estes, Deven P. ; Vannucci, Aaron K. ; Hall, Ariel R. ; Lichtenberger, Dennis L. ; Norton, Jack R. / Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os). In: Organometallics. 2011 ; Vol. 30, No. 12. pp. 3444-3447.
@article{7152d8e9b2514a1d9b6d012a419fcbaf,
title = "Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os)",
abstract = "Several different pKa values for the complex (η5-C5H5)Fe(CO)2H (FpH) in acetonitrile are present in the literature, ranging over 7 orders of magnitude. As a result, the energy of its Fe-H bond is also in dispute, making it difficult to predict the reactivity of this complex. The pKa, bond dissociation enthalpy, bond dissociation free energy, and hydricity of FpH have been measured. The pKa values of analogous group 8 hydrides have been determined, and the energies of the M-H bonds and the hydricity of FpH have been established.",
author = "Estes, {Deven P.} and Vannucci, {Aaron K.} and Hall, {Ariel R.} and Lichtenberger, {Dennis L.} and Norton, {Jack R.}",
doi = "10.1021/om2001519",
journal = "Organometallics",
T1 - Thermodynamics of the metal-hydrogen bonds in (η5-C 5H5)M(CO)2H (M = Fe, Ru, Os)
AU - Estes, Deven P.
AU - Vannucci, Aaron K.
AU - Hall, Ariel R.
AU - Lichtenberger, Dennis L.
AU - Norton, Jack R.
N2 - Several different pKa values for the complex (η5-C5H5)Fe(CO)2H (FpH) in acetonitrile are present in the literature, ranging over 7 orders of magnitude. As a result, the energy of its Fe-H bond is also in dispute, making it difficult to predict the reactivity of this complex. The pKa, bond dissociation enthalpy, bond dissociation free energy, and hydricity of FpH have been measured. The pKa values of analogous group 8 hydrides have been determined, and the energies of the M-H bonds and the hydricity of FpH have been established.
AB - Several different pKa values for the complex (η5-C5H5)Fe(CO)2H (FpH) in acetonitrile are present in the literature, ranging over 7 orders of magnitude. As a result, the energy of its Fe-H bond is also in dispute, making it difficult to predict the reactivity of this complex. The pKa, bond dissociation enthalpy, bond dissociation free energy, and hydricity of FpH have been measured. The pKa values of analogous group 8 hydrides have been determined, and the energies of the M-H bonds and the hydricity of FpH have been established.
U2 - 10.1021/om2001519
DO - 10.1021/om2001519
JO - Organometallics
JF - Organometallics