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Dalton Transactions
Organo-f-element catalysts for efficient and highly selective hydroalkoxylation and hydrothiolation
Charles J. Weissa and Tobin J. Marks*a
* Corresponding authors
a Department of Chemistry, Northwestern University, Evanston, Illinois, USA
E-mail: t-marks@northwestern.edu
Lanthanide and actinide catalysts have made significant contributions to many areas of homogeneous catalysis with hydroelementation of C–C unsaturation being a notable area of success. In this Perspective, we review recent advances in f-element hydroelementation for highly selective hydroalkoxylation and hydrothiolation processes. As will be discussed, f-element hydroalkoxylation and hydrothiolation catalysts exhibit selectivities unobtainable by many late transition metal complexes. First, we review lanthanide-mediated hydroalkoxylation processes with mechanistic, thermodynamic, and kinetic considerations discussed, and then compare/contrast them with analogous C–N and C–P bond-forming transformations. In addition, computational studies are discussed which provide further insight into this transformation and the observed selectivities. Next, actinide-mediated alkyne hydrothiolation is reviewed with a similar discussion of reactivity, mechanism, and thermodynamics.
This article is part of the themed collection: New horizons in organo-f-block chemistry
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https://doi.org/10.1039/C003089A
Dalton Trans., 2010,39, 6576-6588
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C. J. Weiss and T. J. Marks, Dalton Trans., 2010, 39, 6576
DOI: 10.1039/C003089A
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