It's the title couple played by Brad Pitt & Angelina Jolie in a 2005 movie
& Mrs. Smith' Moments That Prove Brad Pitt & Angelina Jolie ... [PAR] Jun 11, 2015 ... Who knew that playing husband and wife in a little movie called Mr. and Mrs. 
Smith would lead to the epic real-life marriage of Brad Pitt and Angelina Jolie?