Q:

Relocate the .pst and .ost from Outlook

Currently, Outlook is storing my .pst file in C:\Users\Daniel\AppData\Local\Microsoft\Outlook but I would much rather it be placed elsewhere (C:\ is an SSD, and I have a D:\ that is a regular drive, and I would much rather than be used in stead).
How can I move the file permanently?

A:

Moving the ost-file in Outlook 2013 is no longer possible via the interface in Outlook. Instead, the quickest way to go would be to create Symbolic Links instead.
With a Symbolic Link, you’d be creating a “pseudo file” which is only a pointer to the actual file. This differs from a shortcut as a shortcut is actually a link-file whereas a Symbolic Link will retain the original file name.
This may sound all very complex, but the actual process is quite easy and very effective. You’ll find step-by-step instructions in the guide: Moving an IMAP pst-file or Hotmail ost-file.
Note: Don’t place the ost-file on a network share. This is unsupported and it would defeat the purpose of enabling Cached Exchange Mode. The ost-file should reside on an internal drive.
(source)

